74317-85-4

Basic information

• Product Name: 3-(2-AMINOETHYL)PYRIDINE
• Synonyms: p-Anisicacid, 2-bromo- (6CI);2-Bromo-p-anisic acid, 3-Bromo-4-carboxyanisole;Benzoicacid, 2-broMo-4-Methoxy-
• CAS NO: 74317-85-4
• Molecular Formula: C₈H₇BrO₃
• Molecular Weight: 231.05
• EINECS: 214-589-6
• Product Categories: Pyridine
• Mol File: 74317-85-4.mol
• Article Data: 14

Chemical Properties

• Melting Point: 199℃
• Boiling Point: 313.6 °C at 760 mmHg
• Flash Point: 143.5 °C
• Appearance: /
• Density: 1.625±0.06 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 0.000209mmHg at 25°C
• Refractive Index: 1.583
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 3.12±0.10(Predicted)
• CAS DataBase Reference: 3-(2-AMINOETHYL)PYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2-AMINOETHYL)PYRIDINE(74317-85-4)
• EPA Substance Registry System: 3-(2-AMINOETHYL)PYRIDINE(74317-85-4)

Safety Data

• Hazardous Substances Data: 74317-85-4(Hazardous Substances Data)

Usage

Chemical Properties

off-white powder

InChI:InChI=1/C8H7BrO3/c1-12-5-2-3-6(8(10)11)7(9)4-5/h2-4H,1H3,(H,10,11)

Upstream product

• 36942-56-0 3-bromo-4-methylanisole 
• 89691-67-8 1-(2-bromo-4-methoxyphenyl)ethanone 
• 100-09-4 4-methoxybenzoic acid 
• 4294-95-5 4-methoxyanthranilic acid 
• 17100-65-1 2-bromo-4-methoxybenzoic acid methyl ester 
• 1208075-63-1 2-bromo-4-methoxybenzoic acid ethyl ester 
• 59142-57-3 (2-bromo-4-methoxyphenyl)phenylmethanone 
• 60710-39-6 3-bromo-p-cresol 
• 2398-37-0 3-methoxyphenyl bromide 
• 28547-28-6 2-bromo-4-hydroxybenzoic acid 
• 77-78-1 dimethyl sulfate 
• 140860-51-1 2-bromo-4-methoxy benzonitrile 
• 43192-31-0 2-bromo-4-methoxybenzaldehyde 

Downstream Products

• 88741-40-6 2-Brom-4-methoxybenzoesaurechlorid 
• 17100-65-1 2-bromo-4-methoxybenzoic acid methyl ester 
• 1446086-67-4 benzyl 2-bromo-4-hydroxybenzoate 
• 1446086-68-5 benzyl 2-(3-carbamoylphenyl)-4-hydroxybenzoate 
• 1446086-69-6 cyclohexylcarbamic acid 6-benzyloxycarbonyl-3′-carbamoylbiphenyl-3-yl ester 
• 1425459-40-0 cyclohexylcarbamic acid 3′-carbamoyl-6-carboxybiphenyl-3-yl ester 
• 666747-07-5 2-bromo-N,N-diisopropyl-4-methoxylbenzamide 
• 1307741-22-5 N-butyl-2-bromo-N-[4-(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)phenyl]-4-methoxybenzamide 
• 100009-74-3 N-(2',3',4'-trimethoxyphenethyl)-2-bromo-4-methoxybenzamide 
• 100009-77-6 5-Methoxy-2-(5,6,7-trimethoxy-isoquinolin-1-yl)-benzoic acid 
• 100009-80-1 1-(2'-bromo-4'-methoxyphenyl)-5,6,7-trimethoxy-3,4-dihydroisoquinoline 
• 100009-76-5 1-(2'-methoxycarbonyl-4'-methoxyphenyl)-5,6,7-trimethoxyisoquinoline 
• 100009-78-7 1-(2'-cyano-4'-methoxyphenyl)-5,6,7-trimethoxyisoquinoline 

Relevant articles and documents

Photoinduced Carbon Tetrabromide Initiated Aerobic Oxidation of Substituted Toluenes to Carboxylic Acids

A mild and metal-free procedure is reported for the aerobic oxidation of substituted toluenes to carboxylic acids by using CBr 4 as initiator under irradiation from a 400 nm blue light-emitting diode.

METHOD FOR PRODUCING 2-HALOGENATED BENZOIC ACIDS

The purpose of the present invention is to provide a method for producing 2-halogenated benzoic acids, the method imparting high regioselectivity (high selectivity) and having a shorter reaction time than does the conventional reaction. This method for producing 2-halogenated benzoic acids, in order to achieve the above purpose, is characterized in that benzoic acids and a halogenating agent are reacted in the presence of an alkaline compound, making it possible to highly selectively obtain 2-halogenated benzoic acids.

Impact of electronic modification of the chelating benzylidene ligand in cis-dichloro-configured second-generation olefin metathesis catalysts on their activity

A series of electronically modified second-generation cis-dichloro ruthenium ester chelating benzylidene complexes was prepared, characterized, and benchmarked in a typical ring-opening metathesis polymerization (ROMP) experiment. The electronic tuning of the parent chelating benzylidene ligand (2-ethyl ester benzylidene) was achieved by substitution at the 4- and 5-positions with electron-withdrawing nitro or electron-donating methoxy groups. The effect of the electronic tuning on the cis-trans isomerization process was studied experimentally and theoretically. Density functional theory calculations clearly revealed the influence of electronic modification on the relative stability between the cis and trans isomers, which is decisive for the activity of the studied compounds as initiators in ROMP.