75031-67-3

Basic information

• Product Name: Silane, butoxytris(1-methylethyl)-
• CAS NO: 75031-67-3
• Molecular Formula: C13H30OSi
• Molecular Weight: 230.466
• Mol File: 75031-67-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, butoxytris(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, butoxytris(1-methylethyl)-(75031-67-3)
• EPA Substance Registry System: Silane, butoxytris(1-methylethyl)-(75031-67-3)

Safety Data

• Hazardous Substances Data: 75031-67-3(Hazardous Substances Data)

Upstream product

• 1068-55-9 isopropylmagnesium chloride 
• 71-36-3 butan-1-ol 

Downstream Products

• 13154-24-0 triisopropylsilyl chloride 

Relevant articles and documents

Versatile method for introduction of bulky substituents to alkoxychlorosilanes

The reactions of various alkoxytrichlorosilanes prepared in situ from tetrachlorosilane and alcohols, with Grignard reagents bearing a bulky substituent such as the isopropyl, sec-butyl, and cyclohexyl group afforded triisopropyl-, tri(sec-butyl)-, and tricyclohexylalkoxysilane in high yields. The reactions of n-butoxytrichlorosilane with these Grignard reagents produced triisopropyl-, tri(sec-butyl)-, and tricyclohexyl(n-butoxy)silane in 94%, 96%, and 92% yields, respectively. Methoxymethyldichlorosilane reacted with the same Grignard reagents to give diisopropyl-, di(sec-butyl)-, and dicyclohexylmethoxymethylsilane in 84%, 83%, and 83% yields. Treatment of methoxydimethylchlorosilane with the Grignard reagents readily afforded isopropyl-, sec-butyl-, and cyclohexylmethoxydimethylsilane in excellent yields. Similar treatment of methoxydimethylchlorosilane with tert-butylmagnesium chloride gave tert-butylmethoxydimethylsilane in 62% yield.