76356-92-8Relevant articles and documents
Preparation of 1-Nitro-1,3-dienes via Nitrotrifluoroacetoxylation of 1,3-Dienes
Bloom, A. Jon,Mellor, John M.
, p. 2737 - 2742 (2007/10/02)
1,3-Dienes react with trifluoroacetyl nitrate, generated in situ by reaction of ammonium nitrate with trifluoroacetic anhydride, to give mixtures of 1,2- and 1,4-nitrotrifluoroacetates.Subsequent reaction of these mixtures with a base, e.g. potassium acet
SYNTHESIS OF 1-NITRO-1,3-DIENES VIA NITROTRIFLUOROACETOXYLATION OF 1,3-DIENES
Bloom, A. Jon,Mellor, John M.
, p. 873 - 876 (2007/10/02)
Nitrotrifluoroacetate adducts, obtained from 1,3-dienes by reaction with ammonium nitrate in trifluoroacetic anhydride, readily eliminate to afford 1-nitro-1,3-dienes in high yield.