76380-14-8

Basic information

• Product Name: Benzene, [(1-methylethenyl)sulfonyl]-
• CAS NO: 76380-14-8
• Molecular Formula: C9H10O2S
• Molecular Weight: 182.243
• Mol File: 76380-14-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-methylethenyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-methylethenyl)sulfonyl]-(76380-14-8)
• EPA Substance Registry System: Benzene, [(1-methylethenyl)sulfonyl]-(76380-14-8)

Safety Data

• Hazardous Substances Data: 76380-14-8(Hazardous Substances Data)

Upstream product

• 75-65-0 tert-butyl alcohol 
• 108-98-5 thiophenol 
• 1859-03-6 ethyl benzenesulfinate 
• 4238-09-9 phenyl isopropyl sulfone 
• 3406-03-9 2-(phenylsulfonyl)acetophenone 
• 17872-92-3 (phenylsulfonylmethyl)trimethylsilane 
• 19826-03-0 (1-chloropropan-2-yl)(phenyl)sulfane 
• 78-75-1 1,2-Dibromopropane 
• 873-55-2 sodium benzenesulfonate 
• 27839-91-4 1-phenyl-2-(phenylsulfonyl)-propan-1-one 
• 836-97-5 [(phenyl)sulfonyl][(trifluoromethyl)sulfonyl]methane 
• 74-88-4 methyl iodide 
• 50-00-0 formaldehyd 
• 91787-35-8 1-phenylsulphonyl-1-trimethylsilylethane 

Downstream Products

• 119039-06-4 N,N-diisopropyl-4-(phenylsulfonyl)-4-methylcyclopent-1-enecarboxamide 
• 586-62-9 Terpinolene 
• 3419-02-1 4-methyl-1-isopropenylcyclohex-3-en-1-ol 
• 69333-65-9 (1-Ethoxy-propane-2-sulfonyl)-benzene 
• 89864-85-7 3-methyl-5-trimethylsilyl-1H-pyrazole 

Relevant articles and documents

An economical and convenient synthesis of vinyl sulfones

A general process for the efficient synthesis of vinyl sulfones has been developed using commercially available sulfinic acid sodium salts and dibromides. A variety of phenyl and methyl vinyl sulfones have been formed in good yields, in the absence of any catalyst. Georg Thieme Verlag Stuttgart.

A convenient synthesis of (E)-(1-propenylsulfonyl)benzene

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Synthesis of Alkenes via Peterson Reaction

The α-phenylthiosilanes (2) have been used to prepare the α-silyl anions (1) by reaction with lithium naphthalenide; subsequent condensation with a carbonyl compound gave the alkene (8) via the Peterson reaction.The α-phenylthiosilanes (2) were prepared from n,n-bis(phenylthio)acetals (4) by reaction with lithium naphthalenide and chlorotrimethylsilane.The n,n-bis(phenylthio)acetals (4) were obtained, in turn, from 1,1-bis(phenylthio)acetals (5) by anion formation with butyl-lithium-N,N,N',N'-tetramethylethylenediamine complex in hexane followed by reaction with an alkyl halide.The Peterson reaction was also used to prepare vinyl sulphides (9) and vinyl sulphones (13).