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7647-18-9

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7647-18-9 Usage

Chemical Properties

Different sources of media describe the Chemical Properties of 7647-18-9 differently. You can refer to the following data:
1. colourless to light yellow oily liquid
2. Antimony pentachloride is a noncombustible, colorless to reddish-yellow oily liquid with an offensive odor.

Physical properties

Antimony pentachloride is prepared by passing chlorine gas into molten antimony trichloride:SbCl3 + Cl2 →SbCl5or by the reaction of the element with excess chlorine:2 Sb + 5 Cl2 → 2 SbCl5.

Uses

Different sources of media describe the Uses of 7647-18-9 differently. You can refer to the following data:
1. Antimony(V) chloride is used as a catalyst and an analytical reagent for testing alkaloids and cesium. It is also used as a polymerization catalyst as well as involved in the chlorination of organic compounds. It acts as a Lewis acid and a strong oxidizing agent.
2. As catalyst when replacing a fluorine substituent with chlorine in organic compounds.

General Description

A reddish-yellow fuming liquid with a pungent odor. Fumes are irritating to the eyes and mucous membranes. Solidifies at 37°F. Corrosive to metals and tissue. Used to make other chemicals, and in chemical analysis.

Air & Water Reactions

Fumes in air to form hydrochloric acid. Reacts with water to yield heat and antimony pentaoxide (Sb2O5) and hydrochloric acid [Merck 11th ed. 1989].

Reactivity Profile

Acidic salts, such as ANTIMONY PENTACHLORIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Hazard

Corrosive, fumes in moist air, reacts strongly with organics.

Health Hazard

Inhalation causes irritation of nose and throat. Contact of liquid with eyes or skin causes severe burns. Ingestion causes vomiting and severe burns of mouth and stomach. Overexposure by any route can cause bloody stools, slow pulse, low blood pressure, coma, convulsions, cardiac arrest.

Fire Hazard

Behavior in Fire: Irritating fumes of hydrogen chloride given off when water or foam is used to extinguish adjacent fire.

Safety Profile

Poison by ingestion. Corrosive. Mutation data reported. See ANTIMONY COMPOUNDS and ANTIMONYPII) CHLORIDE. When heated to decomposition it emits very toxic fumes of Cland Sb.

Potential Exposure

It is used in dyeing, coloring metals and in many organic chemical reactions as a catalyst.

Shipping

UN1730 (liquid) Antimony pentachloride, liquid, Hazard class: 8; Labels: 8-Corrosive material. UN1731 (solution) Antimony pentachloride, solutions, Hazard class: 8; Labels: 8-Corrosive material.

Incompatibilities

Decomposes on contact with heat, acids, alkalis, ammonia, water or other forms of moisture producing fumes of hydrogen chloride and antimony. Decomposes above 77 C forming chlorine and antimony trichloride. Attacks many metals in the presence of moisture forming explosive hydrogen gas. Reacts with air forming corrosive vapors.

Waste Disposal

Encapsulate and transfer to an approve landfill. If chemically treated and neutralized, the chemical is amenable to biological treatment at municipal sewage treatment plant. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/ mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

Check Digit Verification of cas no

The CAS Registry Mumber 7647-18-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,6,4 and 7 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 7647-18:
(6*7)+(5*6)+(4*4)+(3*7)+(2*1)+(1*8)=119
119 % 10 = 9
So 7647-18-9 is a valid CAS Registry Number.
InChI:InChI=1/5ClH.Sb/h5*1H;/q;;;;;+5/p-5

7647-18-9 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Aldrich

  • (338877)  Antimony(V)chloride  ≥99.99% trace metals basis

  • 7647-18-9

  • 338877-5G

  • 565.11CNY

  • Detail
  • Aldrich

  • (338877)  Antimony(V)chloride  ≥99.99% trace metals basis

  • 7647-18-9

  • 338877-25G

  • 1,709.37CNY

  • Detail
  • Aldrich

  • (215171)  Antimony(V)chloride  99%

  • 7647-18-9

  • 215171-50G

  • 630.63CNY

  • Detail
  • Aldrich

  • (215171)  Antimony(V)chloride  99%

  • 7647-18-9

  • 215171-250G

  • 1,091.61CNY

  • Detail
  • Aldrich

  • (215171)  Antimony(V)chloride  99%

  • 7647-18-9

  • 215171-1KG

  • 3,228.03CNY

  • Detail
  • Aldrich

  • (249858)  Antimony(V)chloridesolution  1.0 M in methylene chloride

  • 7647-18-9

  • 249858-100ML

  • 1,026.09CNY

  • Detail

7647-18-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name pentachloro-λ<sup>5</sup>-stibane

1.2 Other means of identification

Product number -
Other names SbCl5

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7647-18-9 SDS

7647-18-9Synthetic route

SbCl5*SO3
25362-97-4

SbCl5*SO3

A

pyrosulfuryl chloride
7791-27-7

pyrosulfuryl chloride

B

2SbCl4(1+)*SO4(2-)=(SbCl4)2SO4

2SbCl4(1+)*SO4(2-)=(SbCl4)2SO4

C

antimonypentachloride
7647-18-9

antimonypentachloride

D

sulfur trioxide
7446-11-9

sulfur trioxide

Conditions
ConditionsYield
70°C in vac.;A n/a
B n/a
C n/a
D 95%
antimony(III) chloride
10025-91-9

antimony(III) chloride

nitrosylchloride
2696-92-6

nitrosylchloride

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
In melt Reaction of SbCl3 melt with NOCl to give SbCl5;80%
With chlorine In melt Reaction of SbCl3 melt with a mixt. of NOCl and Cl2 to give SbCl5;
silver(I) fluoride

silver(I) fluoride

A

disulfur difluoride
13709-35-8

disulfur difluoride

B

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With sulfur with melted Ag2F2 at 500°C; gaseous S2F2 formed;A 48.9%
B n/a
With sulfur with melted Ag2F2 at 600°C; gaseous S2F2 formed;A 40.6%
B n/a
With sulfur with melted Ag2F2 at 140-400°C; gaseous S2F2 formed;A 65-67
B n/a
With sulfur with melted Ag2F2; geseous S2F2 formed;
With S with melted Ag2F2; geseous S2F2 formed;
antimony
7440-36-0

antimony

A

antimonypentachloride
7647-18-9

antimonypentachloride

B

antimony(III) chloride
10025-91-9

antimony(III) chloride

Conditions
ConditionsYield
With chlorine with dry Cl2; refluxing over Sb; distn.;
With hydrogenchloride; dihydrogen peroxide In not given powdered Sb reacts with HCl soln. containing H2O2;
With Cl2 with dry Cl2; refluxing over Sb; distn.;
In not given
antimony
7440-36-0

antimony

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With chlorine heating; distillation;
With chlorine moderatly heating with dry Cl2; fire phonomenon;
With Cl2 heating; distillation;
antimony
7440-36-0

antimony

A

antimony(III) sulfide

antimony(III) sulfide

B

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With thionyl chloride byproducts: SO2, S2Cl2; SbCl3 and Sb2O3 formed in cold with excess of pwdered Sb; Sbl5 formed wth excess of SOCl2 in a sealed tube;
antimony
7440-36-0

antimony

selenium oxychloride
7791-23-3

selenium oxychloride

A

antimonypentachloride
7647-18-9

antimonypentachloride

B

antimony(III) chloride
10025-91-9

antimony(III) chloride

C

diselenium dichloride
10025-68-0

diselenium dichloride

Conditions
ConditionsYield
with excess of SeOCl2;A 0%
B n/a
C n/a
antimony
7440-36-0

antimony

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

A

antimonypentachloride
7647-18-9

antimonypentachloride

B

antimony(III) chloride
10025-91-9

antimony(III) chloride

Conditions
ConditionsYield
With hydrogenchloride In water
With HCl In water
antimony pentafluoride
7783-70-2

antimony pentafluoride

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
over 100 °C; molibdenum fluoride forming as by-product;
over 100 °C; molibdenum fluoride forming as by-product;
antimony(III) chloride
10025-91-9

antimony(III) chloride

A

antimony
7440-36-0

antimony

B

antimonic acid

antimonic acid

C

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With nitric acid In hydrogenchlorideA 0%
B n/a
C n/a
In hydrogenchloride
antimony(III) chloride
10025-91-9

antimony(III) chloride

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With chlorine In melt Reaction of SbCl3 melt with Cl2 to give SbCl5;93-94
With chlorine distillation;
With chlorine with molten SbCl3; distillation;
antimony(III) chloride
10025-91-9

antimony(III) chloride

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
In melt Reaction of SbCl3 melt with NO2 to give SbCl5;
hydrogenchloride
7647-01-0

hydrogenchloride

potassium antimony(III) tartrate

potassium antimony(III) tartrate

A

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
In neat (no solvent) stream of HCl; strong evolution of heat;;
In neat (no solvent) stream of HCl; strong evolution of heat;;
diantimony tetraoxide

diantimony tetraoxide

chlorine
7782-50-5

chlorine

A

antimony pentoxide

antimony pentoxide

B

antimonypentachloride
7647-18-9

antimonypentachloride

C

antimony(III) chloride
10025-91-9

antimony(III) chloride

Conditions
ConditionsYield
In neat (no solvent) Kinetics; react. at 200°C;
native antimony

native antimony

A

antimonypentachloride
7647-18-9

antimonypentachloride

B

antimony(III) chloride
10025-91-9

antimony(III) chloride

Conditions
ConditionsYield
With aqua regia
With aqua regia
antimony(III) trioxide

antimony(III) trioxide

A

phosgene
75-44-5

phosgene

B

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With chlorine In tetrachloromethane heating Sb2O3 with a soln. of Cl2 in CCl4 in a sealed tube at 100°C;;
With tetrachloromethane; chlorine at 100°C in sealed tube;
With Cl2 In tetrachloromethane heating Sb2O3 with a soln. of Cl2 in CCl4 in a sealed tube at 100°C;;
With Cl2; CCl4 at 100°C in sealed tube;
antimony(III) trioxide

antimony(III) trioxide

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With thionyl chloride byproducts: SO2; with large excess of SOCl2;
With SOCl2 byproducts: SO2; with large excess of SOCl2;
antimony(III) trioxide

antimony(III) trioxide

A

cervantite

cervantite

B

antimonypentachloride
7647-18-9

antimonypentachloride

C

antimony(III) chloride
10025-91-9

antimony(III) chloride

Conditions
ConditionsYield
With chlorine by heating;
With Cl2 by heating;
antimony(III) sulfide

antimony(III) sulfide

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With chlorine0%
With Cl20%
antimony
7440-36-0

antimony

selenium
7782-49-2

selenium

A

SbCl5*SeCl4

SbCl5*SeCl4

B

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
With chlorine dry Cl2; remowing SbCl5 over H2SO4;
With Cl2 dry Cl2; remowing SbCl5 over H2SO4;
tetrachloromethane
56-23-5

tetrachloromethane

antimony pentoxide

antimony pentoxide

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
at 420°C;
sulfuryl dichloride
7791-25-5

sulfuryl dichloride

antimony(V) sulfide

antimony(V) sulfide

A

antimonypentachloride
7647-18-9

antimonypentachloride

B

sulfur
7704-34-9

sulfur

Conditions
ConditionsYield
In neat (no solvent)
rhenium(V) chloride
13596-35-5

rhenium(V) chloride

antimony(III) chloride
10025-91-9

antimony(III) chloride

A

rhenium tetrachloride
13569-71-6

rhenium tetrachloride

B

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: Re3Cl9; distiln. (vac.), sublimation;
antimony(III) sulfate

antimony(III) sulfate

A

antimony(III) sulfate * 5 HCl

antimony(III) sulfate * 5 HCl

B

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: SbCl5; passing dry HCl-stream over Sb2(SO4)3 with spontaneous heat evolution (up to melting temp.); cooling;; SbCl5 sublimes;;
In neat (no solvent) byproducts: SbCl5; passing dry HCl-stream over Sb2(SO4)3 with spontaneous heat evolution (up to melting temp.); cooling;; SbCl5 sublimes;;
SbCl5*2SbF5

SbCl5*2SbF5

nitrosylchloride
2696-92-6

nitrosylchloride

A

antimony pentoxide

antimony pentoxide

B

SbF5*NOF

SbF5*NOF

C

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
without moisture of air; heating to 100 °C then in vac. (1-3 mmHg) at 180-200 °C (6h); max. purity 90%;
without moisture of air; heating to 100 °C then in vac. (1-3 mmHg) at 180-200 °C (6h); max. purity 90%;
antimony(III) trioxide

antimony(III) trioxide

cesium hexachloro-stannate(IV)

cesium hexachloro-stannate(IV)

A

caesium oxochlorostannate(IV)

caesium oxochlorostannate(IV)

B

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
Cl2 atm;
Cl2 atm;

A

antimonypentachloride
7647-18-9

antimonypentachloride

B

antimony(III) chloride
10025-91-9

antimony(III) chloride

Conditions
ConditionsYield
heating at 20 Torr;
Sb3OCl13

Sb3OCl13

A

antimony pentoxide

antimony pentoxide

B

antimonypentachloride
7647-18-9

antimonypentachloride

C

antimony(III) chloride
10025-91-9

antimony(III) chloride

Conditions
ConditionsYield
byproducts: Cl2; with heating; SbCl3 and SbCl5 evaporate;
18-crown-6 ether
17455-13-9

18-crown-6 ether

antimonypentachloride
7647-18-9

antimonypentachloride

lead(II) chloride

lead(II) chloride

{Pb(O6(CH2)12)(CH3CN)3}(2+)*2(SbCl6)(1-)={Pb(O6(CH2)12)(CH3CN)3}{SbCl6}2

{Pb(O6(CH2)12)(CH3CN)3}(2+)*2(SbCl6)(1-)={Pb(O6(CH2)12)(CH3CN)3}{SbCl6}2

Conditions
ConditionsYield
In acetonitrile PbCl2 is dissolved by injection of SbCl5 in MeCN, addn. of 18-crown-6; concn. the volume under vac., standing for some time at 20°C, filtn., elem. anal.;100%
sulfuryl dichloride
7791-25-5

sulfuryl dichloride

antimonypentachloride
7647-18-9

antimonypentachloride

tris[2-(2-pyridyl)phenyl]stibine

tris[2-(2-pyridyl)phenyl]stibine

C33H24N3Sb(2+)*2Cl6Sb(1-)

C33H24N3Sb(2+)*2Cl6Sb(1-)

Conditions
ConditionsYield
Stage #1: sulfuryl dichloride; tris[2-(2-pyridyl)phenyl]stibine In acetonitrile at -40℃; for 2h; Inert atmosphere;
Stage #2: antimonypentachloride In dichloromethane at -40℃; for 2h; Inert atmosphere;
100%
hydrogenchloride
7647-01-0

hydrogenchloride

antimonypentachloride
7647-18-9

antimonypentachloride

water
7732-18-5

water

H2O*H(1+)*SbCl6(1-)=H2O*HSbCl6
53890-32-7

H2O*H(1+)*SbCl6(1-)=H2O*HSbCl6

Conditions
ConditionsYield
In dichloromethane (He atm.) the calculated volumes of CH2Cl2-solns. of SbCl5, H2O and HCl were mixed;99%
hydrogenchloride
7647-01-0

hydrogenchloride

antimonypentachloride
7647-18-9

antimonypentachloride

water
7732-18-5

water

H(1+)*SbCl6(1-)*2H2O=HSbCl6*2H2O

H(1+)*SbCl6(1-)*2H2O=HSbCl6*2H2O

Conditions
ConditionsYield
In dichloromethane (He atm.) the calculated volumes of CH2Cl2-solns. of SbCl5, H2O and HCl were mixed;99%
bromocyane
506-68-3

bromocyane

antimonypentachloride
7647-18-9

antimonypentachloride

Conditions
ConditionsYield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of BrCN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;99%
cyanogen iodide
506-78-5

cyanogen iodide

antimonypentachloride
7647-18-9

antimonypentachloride

SbCl5(ICN)
359860-18-7

SbCl5(ICN)

Conditions
ConditionsYield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of ICN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;99%
CYANAMID
420-04-2

CYANAMID

antimonypentachloride
7647-18-9

antimonypentachloride

SbCl5NCNH2
359860-20-1

SbCl5NCNH2

Conditions
ConditionsYield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of H2NCN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;99%
methylsulphinyl chloride
676-85-7

methylsulphinyl chloride

antimonypentachloride
7647-18-9

antimonypentachloride

methyl(chloro)sulfinylantimony pentachloride
65554-06-5

methyl(chloro)sulfinylantimony pentachloride

Conditions
ConditionsYield
In dichloromethane addn. of SbCl5 in CH2Cl2 at 243 K with stirring to CH3SOCl in CH2Cl2 within 1.5 h, further stirring (1 h); concn. (dynamic vac.), filtration at 233 K, drying (dynamic vac., 273 K);99%
pyridine
110-86-1

pyridine

antimonypentachloride
7647-18-9

antimonypentachloride

SbCl5(C5H5N)
24551-32-4

SbCl5(C5H5N)

Conditions
ConditionsYield
In dichloromethane under N2, SbCl5 was added to equiv. amt. of pyridine in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.;99%
antimonypentachloride
7647-18-9

antimonypentachloride

6-Methyl-7-oxo-8-phenyl-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo<3.3.1>nona-2,3,5(9)-trien-chlorid
75307-82-3

6-Methyl-7-oxo-8-phenyl-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo<3.3.1>nona-2,3,5(9)-trien-chlorid

6-Methyl-7-oxo-8-phenyl-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-2,3,5(9)-trien-chlorid
75307-85-6

6-Methyl-7-oxo-8-phenyl-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-2,3,5(9)-trien-chlorid

Conditions
ConditionsYield
In tetrachloromethane ppt. was recrystd. from CH3CN/CCl4 (1:15); elem. anal.;99%
N,N-dimethylbenzylamine N-oxide
5400-82-8

N,N-dimethylbenzylamine N-oxide

antimonypentachloride
7647-18-9

antimonypentachloride

N,N-dimethylbenzylamine oxide-SbCl5
83616-70-0

N,N-dimethylbenzylamine oxide-SbCl5

Conditions
ConditionsYield
In tetrachloromethane soln. of PhCH2Me2NO in CCl4 added to soln. of SbCl5 in CCl4; filtered, washed with CCl4 and petroleum ether; elem. anal.;99%
antimonypentachloride
7647-18-9

antimonypentachloride

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

((CH3)2SO)SbCl5
23058-09-5

((CH3)2SO)SbCl5

Conditions
ConditionsYield
In tetrachloromethane DMSO and SbCl5 (mole ratio 1:1) were mixed in CCl4 with cooling; the mixt was allowed to stand overnight;; the ppt. was collected by filtration, washed with CCl4, then with petroleum ether; elem. anal.;;98.7%
4-methylaminopent-3-en-2-one
130256-90-5

4-methylaminopent-3-en-2-one

antimonypentachloride
7647-18-9

antimonypentachloride

SbCl5*CH3COCHC(NHCH3)CH3

SbCl5*CH3COCHC(NHCH3)CH3

Conditions
ConditionsYield
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.;98%
antimonypentachloride
7647-18-9

antimonypentachloride

N-isopropyl-4-amino-3-penten-2-one
59487-11-5

N-isopropyl-4-amino-3-penten-2-one

SbCl5*CH3COCHC(NHCH(CH3)2)CH3

SbCl5*CH3COCHC(NHCH(CH3)2)CH3

Conditions
ConditionsYield
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.;98%
antimonypentachloride
7647-18-9

antimonypentachloride

6,8-Dimethyl-7-oxo-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo<3.3.1>nona-2,3,5(9)-trien-chlorid
72160-17-9

6,8-Dimethyl-7-oxo-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo<3.3.1>nona-2,3,5(9)-trien-chlorid

6,8-Dimethyl-7-oxo-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-2,3,5(9)-trien-hexachloroantimonat
75307-83-4

6,8-Dimethyl-7-oxo-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-2,3,5(9)-trien-hexachloroantimonat

Conditions
ConditionsYield
In tetrachloromethane ppt. was recrystd. from CH3CN/CCl4 (1:15); elem. anal.;98%
18-crown-6 ether
17455-13-9

18-crown-6 ether

antimonypentachloride
7647-18-9

antimonypentachloride

lead(II) chloride

lead(II) chloride

{Pb(O5(CH2)10)2}(2+)*2(SbCl6)(1-)={Pb(O5(CH2)10)2}{SbCl6}2

{Pb(O5(CH2)10)2}(2+)*2(SbCl6)(1-)={Pb(O5(CH2)10)2}{SbCl6}2

Conditions
ConditionsYield
In acetonitrile PbCl2 is dissolved by injection of SbCl5 in MeCN, addn. of 15-crown-5; concn. the volume under vac., filtn., cooling the filtrate, filtn., washing with MeCN, vac. drying, elem. anal.;97%
4-(ethylamino)penten-2-one
50967-59-4

4-(ethylamino)penten-2-one

antimonypentachloride
7647-18-9

antimonypentachloride

SbCl5*CH3COCHC(NHC2H5)CH3

SbCl5*CH3COCHC(NHC2H5)CH3

Conditions
ConditionsYield
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.;97%
Isopropylmethylcyanamide
54434-25-2

Isopropylmethylcyanamide

antimonypentachloride
7647-18-9

antimonypentachloride

antimony pentachloride-isopropylmethylcyanamide
89953-15-1

antimony pentachloride-isopropylmethylcyanamide

Conditions
ConditionsYield
In dichloromethane addn. dropwise, stirring -78°C for 1 h, then 22°C for 2h,; evapn. in vac., pptn.with pentane, washed with pentane, recrystn. from CH2Cl2, elem.anal.;97%
N-methyl-N-cyclohexyl cyanamide
49677-01-2

N-methyl-N-cyclohexyl cyanamide

antimonypentachloride
7647-18-9

antimonypentachloride

antimony pentachloride-cyclohexylmethylcyanamide
89953-16-2

antimony pentachloride-cyclohexylmethylcyanamide

Conditions
ConditionsYield
In dichloromethane addn. dropwise, stirring -78°C for 1 h, then 22°C for 2h,; evapn., in vac., pptn. with pentane, washed with pentane, recrystn. from CH2Cl2, elem.anal.;97%
styrene
292638-84-7

styrene

2,2'-dipyridyldiselenide
59957-75-4

2,2'-dipyridyldiselenide

antimonypentachloride
7647-18-9

antimonypentachloride

bis(3-phenyl-2,3-dihydro[1,3]selenazolo[3,2-a]pyridinium-4) pentachloroantimonate(III)

bis(3-phenyl-2,3-dihydro[1,3]selenazolo[3,2-a]pyridinium-4) pentachloroantimonate(III)

Conditions
ConditionsYield
In dichloromethane soln. of SbCl5 in CH2Cl2 added to soln. of Se-compound in CH2Cl2 at -40°C with stirring under Ar, stirred for 15 min at -40°C, CH2Cl2 soln. of styrene added dropwise, stirred for 30 min, warmed to room temp.; solvent evapd. in vacuo, recrystd. from CH2Cl2; elem. anal.;97%
dichloromethane
75-09-2

dichloromethane

antimonypentachloride
7647-18-9

antimonypentachloride

chlorine
7782-50-5

chlorine

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

1,2-bis-(diphenylphosphino)ethane
1663-45-2

1,2-bis-(diphenylphosphino)ethane

C26H24Cl2P2(2+)*CH2Cl2*2C2H4Cl2*Cl5Sb(2-)

C26H24Cl2P2(2+)*CH2Cl2*2C2H4Cl2*Cl5Sb(2-)

Conditions
ConditionsYield
Stage #1: chlorine; 1,2-dichloro-ethane; 1,2-bis-(diphenylphosphino)ethane In 1,2-dichloro-ethane at -30℃; for 0.0833333h;
Stage #2: dichloromethane; antimonypentachloride In dichloromethane; 1,2-dichloro-ethane at -30 - 23℃; for 1h;
97%
1,2-bis(methylthio)ethane
6628-18-8

1,2-bis(methylthio)ethane

antimonypentachloride
7647-18-9

antimonypentachloride

C4H10ClS2(1+)*Cl6Sb(1-)

C4H10ClS2(1+)*Cl6Sb(1-)

Conditions
ConditionsYield
Stage #1: 1,2-bis(methylthio)ethane With chlorine In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Inert atmosphere;
Stage #2: antimonypentachloride In dichloromethane at 23℃; for 1h; Inert atmosphere;
97%
antimonypentachloride
7647-18-9

antimonypentachloride

potassium isopropoxide
6831-82-9

potassium isopropoxide

KSb(OCHCH3CH3)6

KSb(OCHCH3CH3)6

Conditions
ConditionsYield
In chloroform byproducts: KCl; A soln. of potassium metal in isopropanol is added to an ice cold soln. of SbCl5, refluxed for 4 h under dry N2, cooling.; KCl is filtered off, elem. anal.;96%
antimonypentachloride
7647-18-9

antimonypentachloride

nitrosylchloride
2696-92-6

nitrosylchloride

nitrosonium hexachloroantimonate
16871-80-0

nitrosonium hexachloroantimonate

Conditions
ConditionsYield
In dichloromethane 0 - 10 °C, under N2; the product was filtered under N2, washed with CH2Cl2, dried in vac. at25 °C, elem. anal.;96%
p-toluamidoxime
19227-13-5

p-toluamidoxime

antimonypentachloride
7647-18-9

antimonypentachloride

SbCl5N(OH)C(NH2)C6H4CH3
132293-63-1

SbCl5N(OH)C(NH2)C6H4CH3

Conditions
ConditionsYield
In dichloromethane addn. of ligand soln. to soln. of SbCl5, pptn., stirred for 1h; ppt. filtered, washed with CH2Cl2, recrystd. from CHCl3/hexane, dried in vac. at 50°C; elem. anal.;96%
4-bromo-N,N-dimethylaniline
586-77-6

4-bromo-N,N-dimethylaniline

antimonypentachloride
7647-18-9

antimonypentachloride

4-bromo-N,N-dimethylaniline antimony pentachloride complex

4-bromo-N,N-dimethylaniline antimony pentachloride complex

Conditions
ConditionsYield
In chloroform stirring for 30 min; filtration of ppt., washing with CHCl3, drying, elem. anal.;96%
1,2-bis(ethylthio)ethane
5395-75-5

1,2-bis(ethylthio)ethane

antimonypentachloride
7647-18-9

antimonypentachloride

C6H14ClS2(1+)*Cl6Sb(1-)

C6H14ClS2(1+)*Cl6Sb(1-)

Conditions
ConditionsYield
Stage #1: 1,2-bis(ethylthio)ethane With chlorine In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Inert atmosphere;
Stage #2: antimonypentachloride In dichloromethane at 23℃; for 1h; Inert atmosphere;
96%
antimonypentachloride
7647-18-9

antimonypentachloride

thioacetamide
62-55-5

thioacetamide

antimony(III) sulfide

antimony(III) sulfide

Conditions
ConditionsYield
With HCl In water High Pressure; SbCl5 dissolved in HCl at ambient temp.; H2O added; temp. increased to 50°C; mixed with stoich. amt. of thioacetamide; soln. transferred into stainless-steel autoclave; sealed autoclave maintained at 180°C for 3 h; cooled to room temp.; filtered; washed (soln. of tartaric acid, H2O); dried (vac.) at 60°C for 5 h;95%
Se2NCl3

Se2NCl3

antimonypentachloride
7647-18-9

antimonypentachloride

{ClSeNSeCl}(1+)*SbCl6(1-)={ClSeNSeCl}SbCl6
151654-58-9, 603109-87-1

{ClSeNSeCl}(1+)*SbCl6(1-)={ClSeNSeCl}SbCl6

Conditions
ConditionsYield
In sulfur dioxide N2-atmosphere; addn. of 1 equiv. SbCl5 to Se2NCl3 soln., stirring (room temp., 2 h); solvent removal (reduced pressure);95%

7647-18-9Relevant articles and documents

Feigl,Schummer

, p. 249 - 249 (1924)

On tetrachlorophosphonium chlorometallates of rhenium and molybdenum: Syntheses, crystal structures, and magnetism of [PCl4]2[Re2Cl10] and [PCl4]3[ReCl6]2, and the magnetic properties of [PCl4]2[Mo2Cl10]

Beck,Mueller-Buschbaum,Wolf

, p. 975 - 981 (2008/10/08)

MoCl4, ReCl4, and ReCl5 react with PCl5 in sealed glass ampoules at temperatures between 220° and 320° to [PCl4]2[Mo2Cl10] (1) [PCl4]2[Re2Cl10] (2), and [PCL4]3[ReCl6]2 (3). 2 crystallizes isotypically to the previously reported 1 and the respective titanium and tin containing analogues. The structure (triclinic, P1 Z = 1, a = 897.3(2), b = 946.0(2), c = 687.13(9) pm, α = 95.59(2)°, β = 95.80(2)°, γ = 101.07(2)°, V = 565.4(2) 106 pm3) is built of tetrahedral [PCl4]+ and edge sharing double octahedral [Re2Cl10]2- ions and can be derived from a hexagonal closest packing of Cl- ions with tetrahedral and octahedral holes partially filled by P(V) and Re(IV), respectively. 3 crystallizes isotypically to [PCL4]3[PCl6][MCl6] (M = Ti, Sn) (tetragonal, P 42/mbc, Z = 4, a = 1496.2(1), c = 1363.2(2) pm). Because no evidence was found for the presence of [PCl6]- ions, Re in 3 has to be of mixed valency with ReIV and ReV sharing the same crystallographic site. The structure can be derived from a cubic closest packing or alternatively from an only sparsely distorted body centered cubic arrangement of Cl- ions which is rarely found for anion arrays. The tetrahedral and octahedral holes are partially filled by PV and MIV/V, respectively. Magnetic measurements show all three compounds to be paramagnetic and confirm the oxidation state IV for Mo and Re in 1 and 2 and the mixed valence (IV/V) for Re in 3.

Ammoxidation of saturated hydrocarbons

-

, (2008/06/13)

The alkanes, e.g., propane, are ammoxidized into admixtures containing α,β-unsaturated nitriles, e.g., admixture of acrylonitrile and propylene, by reacting such alkane with ammonia and oxygen, in vapor phase, in the presence of a catalytically effective amount of a solid catalyst, at least one active catalytic phase of which having the empirical formula (I): optionally also containing iron and/or gallium and/or indium, in which a is a whole or fractional number equal to or greater than 1, b is a whole or fractional number equal to or greater than 0.01, and x is a whole or fractional number provided by the oxidation number of the other elements of the at least one active catalytic phase.

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