768-32-1Relevant articles and documents
Electrosynthese en Chimie Organosilicique: Preparation de Phenyl- et Benzyl-trimethylsilanes
Pons, P.,Biran, C.,Bordeau, M.,Dunogues, J.,Sibille, S.,Perichon, J.
, p. C27 - C29 (1987)
In a single compartment cell fitted with a sacrificial magnesium anode, electrochemical reduction of phenyl and benzyl halides in the presence of trimethylchlorosilane gave the corresponding phenyl- and benzyl-silanes in satisfactory yields.Under well chosen conditions, the synthesis of phenyltrimethylsilane from phenyl bromide or chloride was also found possible.
Preparation method of aromatic silicon organic compound
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Paragraph 0029-0043, (2021/07/08)
The invention provides a preparation method of an aromatic silicon organic compound. The aromatic silicon organic compound is a compound as shown in a formula 3 shown in the specification, the aromatic silicon organic compound is prepared by reacting a compound as shown in a formula 1 with a compound as shown in a formula 2, and the reaction formula is as shown in the specification. In the formulas, a is selected from any integer of 0-5, n is selected from any integer of 1-6, R is selected from one of alkyl, alkoxy, fluorine, trifluoromethyl and trifluoromethoxy; m is any integer selected from 1-3, and R2 is selected from C1-C6 alkyl; a catalyst used in the reaction is MIc, MIc is iodized salt, M is metal ion, and c is selected from 1 or 2 according to the valence state of M; and magnesium is added in the reaction process. The method has the advantages of low cost, effective avoidance of heavy metal residues, simplicity and convenience in operation, high yield, mild reaction conditions and easiness in industrialization.
Nickel-Catalyzed Decarbonylation of Acylsilanes
Ito, Yuri,Kodama, Takuya,Nakatani, Syun,Sakurai, Shun,Tobisu, Mamoru
, p. 7588 - 7594 (2020/06/27)
Nickel-catalyzed decarbonylation of acylsilanes is developed. In sharp contrast to cross-coupling reactions of acylsilanes, in which the silyl group serves as a leaving group, the silyl group is retained in the product in this decarbonylation reaction. Although the strong binding of the dissociated CO to the nickel center frequently hinders catalyst turnover in nickel-mediated decarbonylative reactions, this reaction can be catalyzed by nickel complexes bearing a CO ligand.
Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes
Nagata, Tatsuki,Inoue, Takeru,Lin, Xianjin,Ishimoto, Shinya,Nakamichi, Seiya,Oka, Hideo,Kondo, Ryota,Suzuki, Takeyuki,Obora, Yasushi
, p. 17425 - 17431 (2019/06/24)
N,N-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. N,N-Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can be recycled five times under both hydrosilane and disilane reaction conditions.