77094-42-9

Basic information

• Product Name: 1-(2-hydroxycyclohexyl)-1,4-dioxahexan-6-ol
• Synonyms: 1-(2-hydroxycyclohexyl)-1,4-dioxahexan-6-ol
• CAS NO: 77094-42-9
• Molecular Weight: 204.266
• Mol File: 77094-42-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-(2-hydroxycyclohexyl)-1,4-dioxahexan-6-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-hydroxycyclohexyl)-1,4-dioxahexan-6-ol(77094-42-9)
• EPA Substance Registry System: 1-(2-hydroxycyclohexyl)-1,4-dioxahexan-6-ol(77094-42-9)

Safety Data

• Hazardous Substances Data: 77094-42-9(Hazardous Substances Data)

Upstream product

• 110-83-8 cyclohexene 
• 286-20-4 cyclohexene oxide 
• 111-46-6 diethylene glycol 
• 286-20-4 cyclohexane-1,2-epoxide 
• 14187-32-7 dibenzo-18-crown-6 

Downstream Products

• 17454-53-4 trans cyclohexano-18-crown-6 
• 17454-48-7 cyclohexyl-15-crown-5 

Relevant articles and documents

Radiochemical stability of the dicyclohexano-18-crown-6 ether (DCH18C6): Synthesis and tests in radioactive medium of the DCH18C6 radiolytic products

The cis-syn-cis isomer of the dicyclohexano-18-crown-6 ether (DCH18C6) was subjected to hydrolysis and radiolysis with a 137Cs gamma source, at different doses of irradiation. The cis-syn-cis DCH18C6 radiolytic products previously identified [1], were synthesized in their different configurations. These radiolytic products, all of cis configuration, were tested on aqueous synthetic solutions of spent nuclear fuels. Experiments in radioactive medium showed that, under continuous extraction conditions, the cis-syn-cis DCH18C6 radiolytic products cannot perturb a reprocessing process using the DCH18C6 as selective extractant. Good prospects for the application of DCH18C6 to spent nuclear fuel reprocessing were therefore demonstrated. An X-ray crystallographic study of the DCH18C6 cis-syn-cis-isomer with uranyl nitrate was investigated. Elsevier,.

CATALYTIC HYDROGENATION OF DIBENZO-18-CROWN-6 AT METALS OF THE PLATINUM GROUP

The hydrogenation of the aromatic rings in dibenzo-18-crown-6 is accompanied by hydrogenolysis of the carbon-oxygen bonds of the polyether ring.The selectivity of hydrogenation depends on composition of the solvent, the nature of the catalyst, the temperature, the hydrogen pressure, and other factors.Rhodium and ruthenium catalysts exhibit the highest activity in the reaction: in water, Ru > Rh > Pt, Pd; in 2-propanol, Rh >> Ru > Pt > Pd.The hydrogenation and hydrogenolysis are concurrent reactions, and the former is favored by high pressure.