7790-98-9

Basic information

• Product Name: Ammonium perchlorate
• Synonyms: Perchloricacid, ammonium salt (8CI,9CI);Ammonium perchlorate(NH4ClO4);Arcadene 426;Arcite 155;Arcite 322;Dyno AP;HT 398;NK 270;PChA;PKhA;Perchloricacid,ammoniumsalt
• CAS NO: 7790-98-9
• Molecular Formula: ClO₄*H₄N
• Molecular Weight: 117.48906
• EINECS: 232-235-1
• Mol File: 7790-98-9.mol
• Article Data: 2

Chemical Properties

• Appearance: white crystalline solid or powder
• Density: 1.95 g/cm³
• CAS DataBase Reference: Ammonium perchlorate(CAS DataBase Reference)
• NIST Chemistry Reference: Ammonium perchlorate(7790-98-9)
• EPA Substance Registry System: Ammonium perchlorate(7790-98-9)

Safety Data

• Hazard Codes: O:Oxidizing agent
• Statements: R9:; R44:
• Safety Statements: S14:; S16:; S27:; S36/37:
• RIDADR: 1442
• HazardClass: 5.1
• PackingGroup: II
• Hazardous Substances Data: 7790-98-9(Hazardous Substances Data)

Usage

InChI:InChI=1/ClHO4.H3N/c2-1(3,4)5;/h(H,2,3,4,5);1H3

Synthetic route

perchloric acid (7601-90-3) + hydrazine (302-01-2) → ammonium perchlorate (7790-98-9)

Conditions	Yield
ammonium molybdate In perchloric acid Kinetics; byproducts: N2, HCl; 90°C;

perchloric acid (7601-90-3) + ammonium nitrate → ammonium perchlorate (7790-98-9)

Conditions	Yield
In sulfuric acid; water heating;;

perchloric acid (7601-90-3) + ammonia (7664-41-7) → ammonium perchlorate (7790-98-9)

Conditions	Yield
In water
In not given
In not given pure NH3 introduced in dild. soln. of HClO4;

ammonium chloride + sodium perchlorate → ammonium perchlorate (7790-98-9)

Conditions	Yield
In not given
In not given

ammonium chloride + calcium perchlorate → ammonium perchlorate (7790-98-9)

Conditions	Yield
With calcium hydroxide In not given byproducts: CaCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;
With Ca(OH)2 In not given byproducts: CaCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;

magnesium(II) perchlorate + ammonium chloride → ammonium perchlorate (7790-98-9)

Conditions	Yield
With calcium hydroxide In not given byproducts: MgCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;
With Ca(OH)2 In not given byproducts: MgCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;

perchloric acid (7601-90-3) + bisamminesilver(I) perchlorate (103809-62-7) → ammonium perchlorate (7790-98-9) + silver perchlorate

Conditions	Yield
In water
In water

ammonium carbonate + perchloric acid (7601-90-3) → ammonium perchlorate (7790-98-9)

Conditions	Yield
In water addn. of a calcd. amt. of HClO4 to aq. soln. of (NH4)2CO3 made in freshly distd. water; recrystn. from water, dried in vac. above P2O5 at 110 °C;

hydroxylammonium perchlorate (15588-62-2) → perchloric acid (7601-90-3) + ammonium perchlorate (7790-98-9) + water (7732-18-5) + chlorine (7782-50-5) + dinitrogen monoxide (10024-97-2)

Conditions	Yield
With perchloric acid; ammonia In solid Kinetics; further products; in sealed glass at 80°C; rate of decomp. depends on reagent concn.;
With perchloric acid; ammonia In neat (no solvent) Kinetics; further reagents, further products; in sealed glass (P=25-30 atm.) at 113.5-150.0°C; rate of decomp. depends on conditions and reagent concn.; MAS, IR;

hydroxylammonium perchlorate (15588-62-2) + calcium carbonate → ammonium perchlorate (7790-98-9) + calcium perchlorate

Conditions	Yield
In neat (no solvent) byproducts: N2, CO2, H2O; molar ratio (NH3OH)ClO4:CaCO3=3:1, heating in vac. (110-130°C, 3.5 h, then 130-145°C, 2 h);

ammonium nitrate + sodium perchlorate → ammonium perchlorate (7790-98-9)

Conditions	Yield
In not given
In not given

ammonium sulfate + sodium perchlorate → ammonium perchlorate (7790-98-9)

Conditions	Yield
In water byproducts: Na2SO4; in an exothermic reaction; fractionated crsytn.;
In water byproducts: Na2SO4; in an exothermic reaction; fractionated crsytn.;

ammonium sulfate + barium(II) perchlorate → ammonium perchlorate (7790-98-9)

Conditions	Yield
In not given
In not given

potassium perchlorate → ammonium perchlorate (7790-98-9)

Conditions	Yield
In not given react. of NH4-silico fluoride with KClO4-soln.;;
In not given react. of NH4-silico fluoride with KClO4-soln.;;

ammonium hexafluorosilicate + potassium perchlorate → ammonium perchlorate (7790-98-9)

Conditions	Yield
In not given
In not given

perchloric acid (7601-90-3) + ammonium hydroxide → ammonium perchlorate (7790-98-9)

Conditions	Yield
In water
In water H2O added to 70% aq. HClO4, 25% aq. soln. of NH3 slowly added; crystn. on cooling in refrigerator for 3 d;
In water NH4OH added to aq. soln. of HClO4; crystd., SEM, DTA;
In water

perchloric anhydride (12015-53-1) → ammonium chlorate (10192-29-7) + ammonium perchlorate (7790-98-9)

Conditions	Yield
With ammonia In tetrachloromethane byproducts: NH4Cl; vigorous reaction;; pptn. of the salts;;
With NH3 In tetrachloromethane byproducts: NH4Cl; vigorous reaction;; pptn. of the salts;;

perchloric acid (7601-90-3) + Ag-perchlorate*3NH3 → ammonium perchlorate (7790-98-9) + silver perchlorate

Conditions	Yield
In water
In water

{Cu(NH3)4}(2+)*2ClO4(1-)*2H2O={Cu(NH3)4}(ClO4)2*2H2O → ammonium perchlorate (7790-98-9) + ammonia (7664-41-7) + copper(II) oxide

Conditions	Yield
In water on boiling the aq. soln.;;
In water on boiling the aq. soln.;;

hydroxylammonium perchlorate monohydroxylamminate → ammonium perchlorate (7790-98-9) + water (7732-18-5) + dinitrogen monoxide (10024-97-2)

Conditions	Yield
In methanol Kinetics; at 106.7°C;
With hydroxyammonium sulfate; guanidine nitrate In neat (no solvent) Kinetics; in a sealed glass ampule (P=25-30 atm.) at 101.1-119.8°C; rate of decomposition depends on conditions and reagent concn.; IR;
In ethanol Kinetics; at 106.7°C;
In water Kinetics; at 106.7°C;

ammonium perchlorate (7790-98-9) + caesium methoxide (13106-69-9) → cesium perchlorate (13454-84-7)

Conditions	Yield
In methanol byproducts: NH3, CH3OH; all manipulations in Ar atm.; soln. of CsOMe in MeOH added to soln. of NH4 compd. in MeOH at -40 - -50°C; concd., filtered or pumped to dryness at 25°C;	99%

ammonium perchlorate (7790-98-9) + tris(2-aminoethanol) chromium(III) complex trihydrate (38819-71-5) → [Cr2(Eta)(EtaH)3](ClO4)3 (86852-63-3)

Conditions	Yield
In water Cr complex was added to satd. aq. NH4I; react. time 30 min; elem. anal.;	94%

ammonium perchlorate (7790-98-9) + [Co(1,7-bis(2-pyridyl)-2,6-bis(2-hydroxy-3-hydroxymethyl-5-methylbenzyl)-2,6-diazaheptane(-2H))] (1226763-88-7) → [Co(1,7-bis(2-pyridyl)-2,6-bis(2-hydroxy-3-hydroxymethyl-5-methylbenzyl)-2,6-diazaheptane(-2H))]ClO4*4H2O

Conditions	Yield
With O2 In acetonitrile O2 bubbled through a suspn. of Co complex, stirred; filtered, a soln. of NH4ClO4 in MeCN added, sepd., washed (EtOH, Et2O, hexane), dried (vac.), recrystd. (MeCN/EtOH); elem. anal.;	94%

ammonium perchlorate (7790-98-9) + palladium diacetate (3375-31-3) + 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo<1,4,8,11>tetraazacyclotetradecine → (16-ethyl-5,6,7,8-tetrahydro-9H-dibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) perchlorate (186396-02-1)

Conditions	Yield
In methanol; water (N2); treating the Pd salt with the ligand 2 h at 20°C in MeOH with stirring, filtration, addn. of H2O and NH4ClO4; filtration, washing (H2O); elem. anal.;	92%

strontium(II) carbonate (1633-05-2) + ammonium perchlorate (7790-98-9) → strontium(II) perchlorate

Conditions	Yield
In neat (no solvent) heating equimolar mixture of SrCO3 and NH4ClO4 12 h at 250°C (.+-.5°C) and 1 - 10 torr;;	90%
In neat (no solvent) heating equimolar mixture of SrCO3 and NH4ClO4 12 h at 250°C (.+-.5°C) and 1 - 10 torr;;	90%
In neat (no solvent) heating equimolar mixture of SrCO3 and NH4ClO4 at 250°C;; extraction with organic solvents like n-butanol or acetone;;	50%
In neat (no solvent) heating equimolar mixture of SrCO3 and NH4ClO4 at 250°C;; extraction with organic solvents like n-butanol or acetone;;	50%

ammonium perchlorate (7790-98-9) + bis(tri-tert-butylphosphine)platinum(0) (60648-70-6) → {PtH(NH3)(P(C(CH3)3)3)2}(1+)*ClO4(1-)={PtH(NH3)(P(C(CH3)3)3)2}ClO4 (85944-38-3)

Conditions	Yield
In tetrahydrofuran stirring of starting compounds in THF under Ar at 25°C for 48 h; all operations under Ar: evapn., addn. of CH2Cl2, filtration (florisil), addn. of pentane, cooling, elem. anal.;	90%
In acetone under Ar at 25°C; elem. anal.;	>99

ammonium perchlorate (7790-98-9) + cis-bis(acetonitrile)bis(acetylacetonato)ruthenium(II) → Ru(C5H7O2)2(CH3CN)2(1+)*ClO4(1-)=[Ru(C5H7O2)2(CH3CN)2]ClO4

Conditions	Yield
With Ce(SO4)2 In dichloromethane; water stirring (room temp., 30 min), filtration, stirring (1 h); liquid sepn., washing (water), CH2Cl2 evapn. (room temp.), cryst., washing (diethyl ether), drying (vac.); elem. anal.;	87.3%

ammonium perchlorate (7790-98-9) + (4S)-2,4,8-trimethyl-5-(3-methyl-3-azabutyl)-2,5,8-triazanonane (95420-20-5) + copper(II) perchlorate → {Cu(NH3)(2,4,8-trimethyl-5-(3-methyl-3-azabutyl)-2,5,8-triaza-4(S)-nonane)}(ClO4)2 (78063-15-7)

Conditions	Yield
With ammonia In water mixt. of ligand, 1 M Cu(ClO4)2, 1 M NH4ClO4 and 25% aq. ammonia stood in refrigerator for more than 3 h; filtered, washed with chilled soln. of 0.3 M NH4ClO4 contained a small amt. of NH3, washed with EtOH and H2O, recrystd. by dissolving in warm 0.5 M HClO4 followed by addition of 25% NH3 (5 times); elem. anal.;	85%

ammonium perchlorate (7790-98-9) + nickel(II) chloride hexahydrate + nickel(II) diethyldithiocarbamate (14267-17-5, 1079097-20-3, 52610-81-8) + Tri(p-tolyl)phosphine (1038-95-5) → bis[tri(4-methylphenyl)phosphine](diethyldithiocarbamato)nickel(II) perchlorate (858518-03-3)

Conditions	Yield
In methanol; acetonitrile a mixture of Ni-complex, NiCl2*6H2O, the phosphine, and NH4ClO4 in acetonitrile-methanol (1:1) refluxed for about 3 h; soln. concentrated; soln. left undisturbed for two days;	85%

4,4'-bipyridine (553-26-4) + ammonium perchlorate (7790-98-9) + Ru(2,2'-bipyridine)2Cl2*2H2O → [((bipy)2(Cl)Ru)2(μ-4,4'-bipyridine)](ClO4)2

Conditions	Yield
In water; ethylene glycol heating of mixt. of 4,4'-bipyridine (1 equiv.) and (RuCl2(bipy)2)*2H2O (2 equiv.) in ethylene glycol on water bath for 7 h; cooling, addn. of satd. aq. soln. of NH4ClO4; centrifuging, washing 3 times with ethanol, drying in vac., elem. anal.;	83%

ammonium perchlorate (7790-98-9) + dinitramide potassium salt → ammonium dinitramide

Conditions	Yield
In methanol saturated soln. pouring together; ppt. filtration off, filtrate concn. (vacuum evapn.), residue recrystn. (dioxane-ethyl acetate);	82%

ammonium perchlorate (7790-98-9) + (CH2N(CH2C5H4N)(CH2C6H2Br(O)CHO))2Zn + 1,5-diamino-3-azapentane (111-40-0) → (CH2N(CH2C5H4N)(CH2C6H2Br(OH)CHNCH2CH2))2NZn(2+)*2ClO4(1-)=[(CH2N(CH2C5H4N)(CH2C6H2Br(OH)CHNCH2CH2))2NZn](ClO4)2

Conditions	Yield
With catalyst: CH3COOH In methanol; ethanol 1 equiv. of amine and 2 equiv. of acetic acid in EtOH were added to stirred suspn. of Zn-salt in MeOH over 1 h, stirring for 3 h, EtOH soln. of excess of NH4ClO4 was added; solid was collected, washed twice with EtOH, twice with Et2O and twice with hexane, recrystn., elem. anal.;	80%

ammonium perchlorate (7790-98-9) + [(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Ni(H2O)(benzoato)2] (872993-25-4) + water (7732-18-5) → [(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Ni(H2O)(benzoato)]ClO4 (932703-94-1)

Conditions	Yield
In acetonitrile under N2; soln. of NH4ClO4 (1 equiv.) in MeCN added to Ni complex in MeCN; N2 purged for 1 h; stirred at ambient temp. overnight; solvent removed under reduced pressure; recrystd. by n-pentane diffusioninto CH2Cl2-H2O soln.; elem. anal.;	80%

ammonium perchlorate (7790-98-9) + 3-[(triphenylphosphine)gold]pentane-2,4-dione → Au(NH3)(P(C6H5)3)(1+)*ClO4(1-)=[Au(NH3)(P(C6H5)3)]ClO4 (194206-63-8)

Conditions	Yield
In tetrahydrofuran byproducts: acetylacetone; dropwise addn. of soln. of Au-complex to suspn. of slight stoich. excessNH4ClO4, stirring at room temp. for 1 h; filtration (Celite), concn., pptn. on Et2O addn., collection (filtration), washing (Et2O), recrystn. (THF and Et2O), washing (pentane); elem. anal.;	76%

ammonium perchlorate (7790-98-9) + cis-{ruthenium(III) (2,2'-bipyridine)2 Cl2}Cl*2H2O → cis-{ruthenium(III) (2,2'-bipyridine)2 Cl2}ClO4 (67968-72-3, 76654-78-9)

Conditions	Yield
In methanol To a soln. of the ruthenium complex, a soln. of NH4ClO4 was added and the mixt. refluxed for 15 min.; concg., cooling, centrifugation, washing with ether, drying in vacuo, elem. anal.;	75%

ammonium perchlorate (7790-98-9) + [Au(acetylacetonato-κC(2))(P(C6H4OMe-4)3)] (138980-34-4) → [Au(NH3)(P(C6H4OMe-4)3)]ClO4 (194206-70-7)

Conditions	Yield
In tetrahydrofuran byproducts: acetylacetone; dropwise addn. of soln. of Au-complex to suspn. of NH4ClO4 at room temp.; filtration, concn., pptn. on Et2O addn.; elem. anal.;	75%

ammonium perchlorate (7790-98-9) + 1-hydroxy-5-aza-2,8,9-oxa-1-germatricycloundecane (71682-43-4) → 1-perchloratogermatrane

Conditions	Yield
In not given reaction in water or MeCN; elem. anal.;	75%

ammonium perchlorate (7790-98-9) + nickel(II) chloride hexahydrate + bis(N-allylcyclohexylcarbodithioato)nickel(II) (1395880-11-1) + ethyl acetate (141-78-6) + triphenylphosphine (603-35-0) → bis(triphenylphosphine)(N-allylcyclohexylcarbodithioato)nickel(II) perchlorate - ethyl acetate (1/0.5)

Conditions	Yield
In dichloromethane; ethyl acetate mixt. of Ni complex, PPh3, NiCl2*6H2O and NH4ClO4 heated at reflux in CH2Cl2/EtOAc (3/1) for ca. 2 h; soln. concd. and filtered, filtrate allowed to evap., ppt. filtered, dried, recrystd. from CH2Cl2/EtOAc; elem. anal.;	75%

ammonium perchlorate (7790-98-9) + nickel(II) perchlorate hexahydrate + Zn((CH3C6H2(O)(CHNHCH3)CH2N(CH2C5H4N)CH2)2)(2+)*2ClO4(1-)=[Zn((CH3C6H2(O)(CHNHCH3)CH2N(CH2C5H4N)CH2)2)](ClO4)2 → [Zn(HNCHC6H2(O)(CH3)CH2N(CH2C5H4N)CH2CH2N(CH2C5H4N)CH2C6H2(CH3)(O)CHNCH3)Ni](2+)*2ClO4(1-)=[ZnC33H36NiN6O2](ClO4)2

Conditions	Yield
With LiOH*H2O In methanol; propan-1-ol; acetonitrile soln. of Ni(ClO)4*6H2O in propanol and LiOH*H2O in MeOH added dropwise to soln. of Zn complex in MeCN, mixt. stirred for 30 min, soln. of NH4ClO4 in propanol added; concd., THF added, washed (propanol, THF, hexane), recrystd. by diffusion of THF into CH3CN, elem. anal.;	72%

ammonium perchlorate (7790-98-9) + 3-[(triphenylphosphine)gold]pentane-2,4-dione + water (7732-18-5) → [(AuPPh3)3(μ-O)]ClO4 + [(AuPPh3)4(μ4-N)]ClO4

Conditions	Yield
In tetrahydrofuran byproducts: acetylacetone; stoich. amts., stirring at room temp. for 1.5 h (source of water unclear); removal of volatiles (vac.), stirring with Et2O for 3 h, collection (filtration), washing (Et2O), drying under N2; elem. anal.;	A n/a B 70%

ammonium perchlorate (7790-98-9) + [Ni(N,N-dicyclohexyldithiocarbamate)2] (14592-16-6) + triphenylphosphine (603-35-0) → [Ni(N,N-dicyclohexyldithiocarbamate)(PPh3)2]ClO4 (880549-31-5)

Conditions	Yield
With NiCl2*6H2O In dichloromethane; acetonitrile mixt. of Ni complex, PPh3, NiCl2*6H2O and NH4ClO4 in MeCN/CH2Cl2 (1/1) was refluxed for 2 h; coincd.; kept for 2 d; filtered; dried over CaCl2; recrystd. (MeCN); elem. anal.;	70%

ammonium perchlorate (7790-98-9) + [Ru(η5-cyclopentadienyl)(triphenylarsine)2Cl] + (P(C6H5)3)2Ni(S2CNCN) (14916-09-7) → (P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(As(C6H5)3)2(1+)*ClO4(1-) = [(P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(As(C6H5)3)2](ClO4)

Conditions	Yield
In methanol; acetone byproducts: NH4Cl; (N2); refluxing 1:1 mixt. of metal complexes (4 h), evapn., extraction (benzene), methanolic ammonium salt addn.; elem. anal.;	70%

ammonium perchlorate (7790-98-9) + [(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Ni(H2O)(benzoato)2] (872993-25-4) → [(6-Ph2TPA)Ni(O2CPh)]ClO4 (932703-85-0)

Conditions	Yield
In acetonitrile byproducts: benzoic acid, H2O, NH3; under N2; soln. of NH4ClO4 (1 equiv.) in MeCN added to Ni complex in MeCN; N2 purged for 1 h; stirred at ambient temp. overnight; solvent removed under reduced pressure; recrystd. by Et2O diffusion intoMeOH-MeCN soln.; detd. by (1)H NMR spectra;	70%

zinc(II) perchlorate + ammonium perchlorate (7790-98-9) + 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo<1,4,8,11>tetraazacyclotetradecine → (16-ethyl-5,6,7,8-tetrahydro-9H-dibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)zinc(II) perchlorate

Conditions	Yield
In methanol; water heating the Zn salt and the ligand 1 h in MeOH with stirring to 50°C, addn. of H2O and NH4ClO4; filtration, washing (H2O); elem. anal.;	69%

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + ammonium perchlorate (7790-98-9) + (P(C6H5)3)2Ni(S2CNCN) (14916-09-7) → (P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(P(C6H5)3)2(1+)*ClO4(1-) = [(P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(P(C6H5)3)2](ClO4)

Conditions	Yield
In methanol; acetone byproducts: NH4Cl; (N2); refluxing 1:1 mixt. of metal complexes (4 h), evapn., extraction (benzene), methanolic ammonium salt addn.; elem. anal.;	68%

ammonium perchlorate (7790-98-9) + nickel(II) chloride hexahydrate + bis(4-methylpiperazinecarbodithioato) nickel(II) + triphenylphosphine (603-35-0) → bis(triphenylphosphine)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate monohydrate (935742-17-9)

Conditions	Yield
In methanol; dichloromethane Ni-complex, PPh3, NiCl2*6H2O and NH4ClO4 refluxed for .apprx.2 h in CH3OH/CH2Cl2 1:1 mixt.; concd.; filtered; kept for evapn.; filtered; dried; recrystallized from CH3OH/CH2Cl2 1:1 mixt.; elem. anal.;	65%

ammonium perchlorate (7790-98-9) + nickel(II) chloride hexahydrate + bis(4-methylpiperazinecarbodithioato) nickel(II) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → 1,2-bis((diphenylphosphino)ethane)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate (935742-19-1)

Conditions	Yield
In methanol; dichloromethane Ni-complex, organic ligand, NiCl2*6H2O and NH4ClO4 refluxed for .apprx.4h in CH3OH/CH2Cl2 1:1 mixt.; concd.; filtered; kept for evapn.; sepd. out after 2 days; recrystallized from CH3OH/CH2Cl2 1:1 mixt.; elem. anal.;	65%

ammonium perchlorate (7790-98-9) + 1,3-di(4-pyridyl)propane (17252-51-6) + water (7732-18-5) + cobalt(II) diacetate tetrahydrate (6147-53-1) → [cobalt(II)(1,3-bis(4-pyridyl)propane)2*2H2O](ClO4)2*H2O*3(1,3-bis(pyridyl)propane)

Conditions	Yield
With 1,3,4-thiadiazole-2,5-di-3-pyridyl In methanol; chloroform; water to soln. of 1,3-bis(4-pyridyl) and 1,3,4-thiadiazole-2,5-di-3-pyridyl inCHCl3/MeOH added soln. of Co(CH3COO)2*4H2O in MeOH and mixt. stirred fo r 20 min; aq. soln. of NH4ClO4 added dropwise and mixt. stirred for 5 min and then filtered; filtrate evapd. at room temp. for 20 d and compd. crystd.; elem. anal.;	65%

ammonium perchlorate (7790-98-9) + (η5-C5H5)RuCl(SbPh3)2 + (P(C6H5)3)2Ni(S2CNCN) (14916-09-7) → (P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(Sb(C6H5)3)2(1+)*ClO4(1-) = [(P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(Sb(C6H5)3)2](ClO4)

Conditions	Yield
In methanol; acetone byproducts: NH4Cl; (N2); refluxing 1:1 mixt. of metal complexes (4 h), evapn., extraction (benzene), methanolic ammonium salt addn.; elem. anal.;	64%

ammonium perchlorate (7790-98-9) + {Co(1,4,7-triazacyclononane)(3-thiapentane-1,5-diamine)}Cl3*H2O → {μ-1,4-diaza-7-azanidocyclononane-1κ(2)N(1),N(4),1:2κ(2)N(7)-μ2-4-thiapentane-1,5-amido-1κS,1:2κ(4)N,N'-1,4,7-triazacyclononane-2κ(3)N(1),N(4),N(7)dicobalt(III)} perchlorate hydrate

Conditions	Yield
With OH(1-) In sodium hydroxide byproducts: H2O; aq. NaOH; soln. Co-complex in 4 M NaOH heated (60°C, 1 h) in a closed teflon tube, cooled (ice), addn. ice-cold water with stirring and cooling (ice), addn. ice-cold 1 M soln. NH4ClO4, pptn.; after 20 min ppt. filtered off, washed (1. ice-cold water, 2. 96% EtOH (3 times), 3. Et2O), dried (air), elem. anal.;	63%

Upstream product

• 7601-90-3 perchloric acid 
• 7664-41-7 ammonia 
• 12015-53-1 perchloric anhydride 
• 15588-62-2 hydroxylammonium perchlorate 
• 103809-62-7 bisamminesilver(I) perchlorate 
• 302-01-2 hydrazine 

Downstream Products

• 2696-92-6 nitrosylchloride 
• 10544-73-7 dinitrogen trioxide 
• 80937-33-3 oxygen 
• 7782-50-5 chlorine 
• 10102-44-0 Nitrogen dioxide 
• 7727-37-9 nitrogen 
• 10049-04-4 chlorine dioxide 
• 7732-18-5 water 
• 7601-90-3 perchloric acid 
• 10024-97-2 dinitrogen monoxide 
• 7647-01-0 hydrogenchloride 
• 7664-41-7 ammonia 
• 10192-29-7 ammonium chlorate 
• 14998-27-7 chlorite 

Relevant articles and documents

Low-temperature thermal decomposition of crystalline partly and completely deuterated ammonium perchlorate

Although ammonium perchlorate, widely used as a rocket propellant, has been extensively investigated for many years, the mechanism of its thermal decomposition at low temperatures remains controversial. Examination of the thermal behaviour of large crystals of partly and completely deuterated ammonium perchlorate by DSC, SEM, TG and QMS reveals that the rates of thermal decomposition depend on the degree of deuteration and decrease in the sequence N[H/D]4ClO4 > NH4ClO4 > ND4ClO4.