78499-87-3

Basic information

• Product Name: bis(chloromagnesiummethyl)benzol
• Synonyms: bis(chloromagnesiummethyl)benzol
• CAS NO: 78499-87-3
• Molecular Weight: 223.668
• Mol File: 78499-87-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: bis(chloromagnesiummethyl)benzol(CAS DataBase Reference)
• NIST Chemistry Reference: bis(chloromagnesiummethyl)benzol(78499-87-3)
• EPA Substance Registry System: bis(chloromagnesiummethyl)benzol(78499-87-3)

Safety Data

• Hazardous Substances Data: 78499-87-3(Hazardous Substances Data)

Upstream product

• 612-12-4 o-Xylylene dichloride 
• 86901-19-1 9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium 

Downstream Products

• 202998-96-7 trans-(PMe₃)2BrPd(CH₂C₆H₄-o-CH₂)PdBr(PMe₃)2 
• 84457-41-0 α,alpha'.-bis(trimethylstannyl)-o-xylene 
• 95911-91-4 iron(η2,η2-o-xylylene)tris((methyl)2(Ph)phosphine) 
• 121954-50-5 1,2-bis[di(t-butyl)phosphinomethyl]benzene 

Relevant articles and documents

Metal Complexes derived from the o-Xylylidene Ligand, o-C6H4(CH2-)2, and the X-Ray Crystal and Molecular Structure of the Metallocycle >

From the new di-Grignard reagent o-C6H4(CH2MgCl)2 (i) the thermally stable metallobenzocyclopentenes (R = Me3Si and M = Ti, Zr, or Hf; or R = H and M = Ti or Zr ) and , (ii) the η1-diacylHf(η-C5H4SiMe3)2

Method of manufacturing phosphine compound

A method of preparing a compound (I) of general formula (R3—C)2P—L1—X—L2—P—(C—R3)2, in which R is independently a pendant, optionally substituted, organic group through which the group is l

Polymer supporeted 'Magnesium(anthracene)': Effective in Forming Benzylic Grignard Reagents (via Electron Transfer Reactions)

A polymer supported 'magnesium(anthracene)' (4) has been prepared from the reaction in tetrahydrofuran (thf) of (1) with polystyrene bearing -9-CH2SiMe2(C14H9) groups (3); the green paramagnetic solid, containing dianion radical anion anthracene sites, yields Grignard reagents (>90percent) with benzylic halides in thf via electron transfer reactions, as does the model compound for the dianion sites, viz. (thf)2> (6).