79-53-8Relevant articles and documents
3-CHLOROPENTAFLUOROPROPENE-1,2-OXIDE: PREPARATION AND REACTIONS WITH SOME HETEROATOM NUCLEOPHILES AND ANTIMONY PENTAFLUORIDE
Kvicala, J.,Paleta, O.
, p. 6721 - 6724 (1994)
Nucleophilic epoxidation of 3-chloropentafluoro-1-propene at PTC conditions afforded 3-chloropentafluoropropene-1,2-oxide, which was reacted with some oxygen and nitrogen nucleophiles to 3-chloro-3,3-difluoropropionic acid derivatives.With antimony pentafluoride, mixture of fluorinated acetones was obtained.
Interaction of perfluorinated α-fluorosulfatocarbonyl compounds with nucleophilic reagents
Delyagina, N. I.,Avetisyan, E. A.,Rogovik, V. M.,Cherstkov, V. F.,Sterlin, S. R.,German, L. S.
, p. 217 - 222 (2007/10/02)
α-Perfluorosulfatoperfluorocarbonyl compounds interact with alkaline metals halogenides to form the corresponding α-halo derivatives as a result of the direct nucleophilic substitution of the FSO3 group.Through the action of halogenide anions on perfluorinated α,β-bis-fluorosulfatocarbonyl compounds, substitution by halogen of the FSO3 group in the α-position to the carbonyl takes place.However, the FSO3 group in the β-position is cleaved, which allows α-substituted β-dicarbonyl derivatives to be obtained.
REDUCTIVE DEFLUORINATION OF HEXAFLUOROACETONE AND THE SYNTHESIS OF HALOPENTAFLUOROACETONES
Postovoi, S. A.,Vol'pin, I. M.,Mysov, E. I.,Zeifman, Yu. V.,German, L. S.
, p. 1067 - 1070 (2007/10/02)
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