79207-42-4

Basic information

• Product Name: 4-ALLYL-1LAMBDA6,4-THIAZINANE-1,1-DIONE
• Synonyms: 4-ALLYL-1LAMBDA6,4-THIAZINANE-1,1-DIONE;4-ALLYLTHIOMORPHOLINE-1,1-DIOXIDE;4-Allylthiomorpholine-1,1-dioxide 98%
• CAS NO: 79207-42-4
• Molecular Formula: C7H13NO2S
• Molecular Weight: 175.25
• Mol File: 79207-42-4.mol
• Article Data: 1

Chemical Properties

• Melting Point: 97-98
• Boiling Point: 319.8 °C at 760 mmHg
• Flash Point: 147.2 °C
• Appearance: /
• Density: 1.143 g/cm³
• Vapor Pressure: 0.000331mmHg at 25°C
• Refractive Index: 1.497
• CAS DataBase Reference: 4-ALLYL-1LAMBDA6,4-THIAZINANE-1,1-DIONE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-ALLYL-1LAMBDA6,4-THIAZINANE-1,1-DIONE(79207-42-4)
• EPA Substance Registry System: 4-ALLYL-1LAMBDA6,4-THIAZINANE-1,1-DIONE(79207-42-4)

Safety Data

• Hazard Codes: Xi
• Statements: R34:Causes burns.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S36/37/39:Wear suitabl
• Hazardous Substances Data: 79207-42-4(Hazardous Substances Data)

Usage

General Description

4-Allyl-1lambda6,4-thiazinane-1,1-dione is a chemical compound with the molecular formula C7H9NO2S. It is a thiazolidinedione derivative, which is commonly used as a building block in organic synthesis. 4-ALLYL-1LAMBDA6,4-THIAZINANE-1,1-DIONE is typically used as a reagent in the synthesis of various pharmaceuticals and other organic molecules. It is known for its potential biological and pharmacological activities, and it has been studied for its potential applications in the treatment of various diseases, including diabetes and cancer. Additionally, it is used in the development of new materials and compounds in the field of organic chemistry and drug discovery.

InChI:InChI=1/C7H13NO2S/c1-2-3-8-4-6-11(9,10)7-5-8/h2H,1,3-7H2

Upstream product

• 77-77-0 Divinyl sulfone 
• 107-11-9 1-amino-2-propene 
• 39093-93-1 thiomorpholine 1,1-dioxide 
• 107-05-1 3-chloroprop-1-ene 

Relevant articles and documents

Concerning the Reactivity of Unsubstituted and Alkyl Substituted Thiomorpholines, 5. On the Joint Action of Elementary Sulfur and Gaseous Ammonia on Ketones, 95

The syntheses of 4-amino-thiomorpholine-1,1-dioxide (12) and 4-hydroxy-thiomorpholine-1,1-dioxide (11) from 1,4-thioxane-1,1-dioxide (1) by pressureless reaction of 1 with hydrazine hydrate and hydroxylamine, resp. is described.In analogy various other N-substituted thiomorpholine-1,1-dioxides are obtained with prim. amines (2-8) and diamines (9,10). 12 condensates with aldehydes (14-24) and ketones (25-29); reaction of 12 with 1 gives N,N'-dithiomorpholine-1,1-dioxide (13).Acylation of 12 with monochlorides (30-35), dichlorides of dicarboxylic acids (36-40) and carbo xylic acid anhydrides (41-43) proceeds smoothly.Compounds 38-43 are cyclic imides.Isocyanates give with 12 the expected compounds 45-48. 12 reacts with chlorinated 1,3,5-triazines to compounds which can be purified only with difficulty (49-51).Quaternization of the N-substituted thiomorpholine-1,1-dioxides with benzylbromide (52,53) and methyliodide (54,55) is possible.Ethylenbromide reacts with 9 to give the bis quaternization product 56.Further reactions of thiomorpholine-1,1-dioxide (57) with sulfuryl chloride (58), bromo cyanide (59), allylic chloride (60), chloro acetonitrile (61) and trityl chloride (62) are described. 11 reacts with carboxylic acid chlorides (63-65) and iso-cyanates (66-70) to yield the expected compounds.Propylene oxide gives with 12 the addition product 71; sulfur dioxide is added to 11 to thiomorpholine-1,1-dioxide sulfonic acid (72). - Keywords: 4-Aminothiomorpholine-1,1-dioxide; 4-Hydroxy-thiomorpholine-1,1-dioxide; Reactivity; Synthesis.