808-12-8Relevant articles and documents
Electrocatalytic reduction of aldehydes and ketones on nickel(II) tetraazamacrocyclic complex-modified graphite felt electrode
Kashiwagi, Yoshitomo,Kikuchi, Chikara,Kurashima, Futoshi,Anzai, Jun-Ichi
, p. 9 - 13 (2007/10/03)
Electrocatalytic reduction of aldehydes and ketones was studied using a nickel(II) tetraazamacrocyclic complex-modified graphite felt (GF) electrode. The nickel(II) tetraazamacrocyclic complex-modified GF electrode was prepared by attaching nickel(II) (6-(2′-hydroxyethyl)-1,4,8,11-tetraazacyclotetradecane)perchlorate chemically to the carboxyl groups of a thin poly(acrylic acid) (PAA) layer coated on the GF. The modified electrode gave a reversible electron transfer for the nickel(II)-nickel(I) redox couple in cyclic voltammetry at -0.95 V versus Ag/AgCl. A preparative electrocatalytic reduction of aldehydes and ketones to the corresponding alcohol and pinacol compounds was successfully achieved on the modified electrode with an adequate current efficiency (46.9-75.9%), conversion (48.1-84.6%) and turnover number of the nickel catalyst (1053-2267).
Novel reduction of carbonyl compounds with Al/NH3/halide under irradiation of ultrasonic wave
Sato,Nagaoka,Goto,Saito
, p. 290 - 292 (2007/10/02)
Various carbonyl compounds, such as benzophenones and acetophenones, were reduced by Al/NH3/halide under ultrasonic wave irradiation to give the corresponding monohydric alcohols and/or pinacols in satisfactory yields. The addition of inorganic halides improved the selectivity in the formation of monohydric alcohols and pinacols.