80885-60-5

Basic information

• Product Name: dl-pinacol
• CAS NO: 80885-60-5
• Molecular Weight: 142.198
• Mol File: 80885-60-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dl-pinacol(CAS DataBase Reference)
• NIST Chemistry Reference: dl-pinacol(80885-60-5)
• EPA Substance Registry System: dl-pinacol(80885-60-5)

Safety Data

• Hazardous Substances Data: 80885-60-5(Hazardous Substances Data)

Upstream product

• 78-94-4 methyl vinyl ketone 

Downstream Products

• 64701-62-8 1-[2-methyl-2-cyclopenten-1-yl]ethanone 
• 1601-02-1 1-(2-methyl-cyclopent-1-enyl)-ethanone-(2,4-dinitro-phenylhydrazone) 

Relevant articles and documents

REDUCTIVE COUPLING OF α,β-ENONES I : REDUCTION OF METHYL-VINYL KETONE AND MESITYL OXIDE.

Reductive coupling of methyl-vinyl ketone with TiCl4-Mg gives pinacol 1 (25percent).According to the reducing agents, mesityl oxide yields 2,4,5,7-tetramethyl-octa-2,4,6-triene 3 (with 4TiCl3-LiAlH4), triene 3 or 2,4,5,7-tetramethyl-octa-2,6-dien-4,5-diol 5 (with TiCl4-Mg), pinacol 5 (with VCl3-Mg), and 2-acetyl-1,3,3,4,4-pentamethyl-cyclopentene 7 (with CrCl3-Mg or FeCl3-Mg or ZrCl4-Mg) as major products.