81720-18-5

Basic information

• Product Name: methyl 2-(4-iodophenoxy)acetate
• Synonyms: methyl 2-(4-iodophenoxy)acetate
• CAS NO: 81720-18-5
• Molecular Formula: C₉H₉IO₃
• Molecular Weight: 292.07
• Mol File: 81720-18-5.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: methyl 2-(4-iodophenoxy)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(4-iodophenoxy)acetate(81720-18-5)
• EPA Substance Registry System: methyl 2-(4-iodophenoxy)acetate(81720-18-5)

Safety Data

• Hazardous Substances Data: 81720-18-5(Hazardous Substances Data)

Upstream product

• 626-02-8 3-Iodophenol 
• 96-32-2 bromoacetic acid methyl ester 
• 2065-23-8 methyl 2-phenoxyacetate 
• 540-38-5 p-Iodophenol 
• 67-56-1 methanol 
• 1878-94-0 4-iodophenoxyacetic acid 

Downstream Products

• 1878-94-0 4-iodophenoxyacetic acid 
• 181220-56-4 4-(3-cyclopentyloxy-4-methoxyphenyl)-1,1-(ethylenedioxy)-4-(2-[4-(1-piperidinocarbonylmethoxy)phenyl]ethynyl)cyclohexane 
• 181220-58-6 4-(2-[4-carbomethoxymethyloxyphenyl]ethynyl)-4-(3-cyclopentyloxy-4-methoxyphenyl)-1,1-(ethylenedioxy)cyclohexane 
• 1257107-63-3 (R)-{4-[3-(1-naphthalen-1-yl-ethylamino)-prop-1-ynyl]-phenoxy}-acetic acid methyl ester 
• 178321-68-1 methyl 2-(4-ethynylphenoxy)acetate 
• 98557-97-2 2H-2,3-dihydro-6-iodobenzo[b]-1,4-oxazin-3-one 
• 932711-44-9 methyl 2-{4-[2-(4-aminophenyl)ethynyl]phenoxy}acetate 

Relevant articles and documents

Design of novel tripyridinophane-based Eu(iii) complexes as efficient luminescent labels for bioassay applications

In this work, the development of highly luminescent europium(iii) complexes in water solution is reported, including their syntheses, analyses of their photophysical properties and applications in bioassays. Three Eu(iii) complexes are derived from new li

Photocatalytic Oxidative Iodination of Electron-Rich Arenes

A visible-light-mediated oxidative iodination of electron-rich arenes has been developed. 2.5 mol% of unsubstituted anthraquinone as photocatalyst were used in combination with elementary iodine, trifluoroacetic acid and oxygen as the terminal oxidant. The iodination proceeds upon irradiation in non- or weakly-electron donating solvents (DCM, DCE and benzene) wherein a spectral window in strongly coloured iodine solutions can be observed at around 400 nm. The method provides good to excellent yields (up to 98%) and shows excellent regioselectivity and good functional group tolerance (triple bonds, ketone, ester, amide). Moreover, the photo-iodination was also upscaled to a 5 mmol scale (1.1 g). Mechanistic investigations by intermediate trapping and competition experiments indicate a photocatalytic arene oxidation and the subsequent reaction with iodine as a likely mechanistic pathway. (Figure presented.).

WATER-SOLUBLE TRIAZAPYRIDINOPHANE-BASED COMPLEXING AGENTS AND CORRESPONDING FLUORESCENT LANTHANIDE COMPLEXES

The invention relates to complexing agents of formula (I) in which A1, A2, A3 and R1 are as defined in the description. The invention also relates to lanthanide complexes obtained from said complexing agents. The invention can be used for marking biological molecules.