81932-05-0Relevant articles and documents
SUR UNE TRANSFORMATION INATTENDUE DU β-METHYL β-NITROSTYRENE EN ALDEHYDE SALICYLIQUE
Guillaumel, Jean,Demerseman, Pierre,Royer, Rene
, p. 4215 - 4218 (1981)
An unexpected route to o-hydroxybenzaldehyde is described.Thus, β-methyl β-nitrostyrene mixed with acetyl chloride and aluminium chloride at 0 deg C yields up to 45percent salicylaldehyde besides 2-acetoximino 1-chloro 1-phenyl propane and dichloromethyl benzene as minor products.