82079-40-1

Basic information

• Product Name: Benzene, 1,3,5-trimethyl-2-[(S)-methylsulfinyl]-
• CAS NO: 82079-40-1
• Molecular Formula: C10H14OS
• Molecular Weight: 182.287
• Mol File: 82079-40-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, 1,3,5-trimethyl-2-[(S)-methylsulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,3,5-trimethyl-2-[(S)-methylsulfinyl]-(82079-40-1)
• EPA Substance Registry System: Benzene, 1,3,5-trimethyl-2-[(S)-methylsulfinyl]-(82079-40-1)

Safety Data

• Hazardous Substances Data: 82079-40-1(Hazardous Substances Data)

Upstream product

• 75-16-1 methylmagnesium bromide 
• 499140-12-4 benzyl (2R,4S,5R)-4-methyl-5-phenyl-1,2,3-oxathiazolidine-2-oxide-3-carboxilate 
• 2633-66-1 2-mesitylmagnesium bromide 
• 7570-91-4 methyl mesityl sulphide 
• 135802-77-6 (S_S)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranosyl methanesulfinate 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 7321-59-7 1,3,5-trimethyl-2-(methylsulfinyl)benzene 
• 934-72-5 Methyl p-tolyl sulfoxide 
• 623-13-2 4-methylphenyl methylsulfide 
• 1541-10-2 mesitylthiol 
• 1308833-75-1 2-(mesitylsulfinyl)ethyl phenyl sulfone 
• 74-88-4 methyl iodide 
• 1308834-16-3 2-(mesitylsulfanyl)ethyl phenyl sulfone 
• 135802-77-6 1,2:5,6-di-O-isopropylidene-α-D-glucofuranosyl-(-)-<(S)S>-methanesulfinate 

Relevant articles and documents

Flexible C2-symmetric bis-sulfoxides as ligands in enantioselective 1,4-addition of boronic acids to electron-deficient alkenes

The application of acyclic C2-symmetric chelating bis-sulfoxide ligands in the Rh(I)-catalyzed enantioselective 1,4-addition of boronic acids to electron-deficient alkenes is reported. Among the acyclic ethane-bridged bis-sulfoxides tested, the

Organocatalytic asymmetric synthesis of sulfoxides from sulfenic acid anions mediated by a cinchona -derived phase-transfer reagent

Preliminary results concerning a conceptually novel route to chiral sulfoxides based on the asymmetric alkylation of sulfenate salts with alkyl halides mediated by a chiral phase-transfer catalyst are described. As a representative example, o-anisyl methyl sulfoxide was produced in 96% yield and with an enantiomeric excess of 58% using commercial cinchonidinium derivative 2a.

Highly enantioselective oxidation of sulfides to sulfoxides by a new oxaziridinium salt

The new oxaziridinium salt 5 (R2 = TBDPS) is an effective reagent for the highly enantioselective oxidation of sulfides to sulfoxides with up to >99% ee and good yields. As such, it represents a new valuable nonmetallic alternative to the existing methods for asymmetric sulfoxidation.