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84466-85-3

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  • SAGECHEM/(S)-1-((1-Methylpyrrolidin-2-yl)methyl)piperidine/SAGECHEM/Manufacturer in China

    Cas No: 84466-85-3

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84466-85-3 Usage

General Description

(S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine, also known as (S)-pmp or (S)-nicotine, is a chemical compound that belongs to the class of pyrrolidine alkaloids. It is the naturally occurring enantiomer of nicotine and is found in various plants such as tobacco and tomatoes. (S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine possesses stimulant and psychoactive properties, and is known to act as a potent agonist of the nicotinic acetylcholine receptor. It is commonly used as a research tool in the study of the central nervous system and as a reference standard in pharmacological studies. Furthermore, (S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine is also utilized in the synthesis of pharmaceuticals and agrochemicals.

Check Digit Verification of cas no

The CAS Registry Mumber 84466-85-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,4,4,6 and 6 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 84466-85:
(7*8)+(6*4)+(5*4)+(4*6)+(3*6)+(2*8)+(1*5)=163
163 % 10 = 3
So 84466-85-3 is a valid CAS Registry Number.
InChI:InChI=1/C11H22N2/c1-12-7-5-6-11(12)10-13-8-3-2-4-9-13/h11H,2-10H2,1H3/t11-/m0/s1

84466-85-3 Well-known Company Product Price

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  • TCI America

  • (M1183)  (S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine  >97.0%(GC)(T)

  • 84466-85-3

  • 1g

  • 750.00CNY

  • Detail
  • TCI America

  • (M1183)  (S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine  >97.0%(GC)(T)

  • 84466-85-3

  • 5g

  • 2,500.00CNY

  • Detail
  • Aldrich

  • (446351)  (S)-1-[(1-Methyl-2-pyrrolidinyl)methyl]piperidine  97%

  • 84466-85-3

  • 446351-1ML

  • 2,127.06CNY

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84466-85-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name (S)-1-Methyl-2-(piperidinomethyl)pyrrolidine

1.2 Other means of identification

Product number -
Other names 1-[[(2S)-1-methylpyrrolidin-2-yl]methyl]piperidine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:84466-85-3 SDS

84466-85-3Downstream Products

84466-85-3Relevant articles and documents

Synthesis of chiral diamines using novel 2-trichloromethyloxazolidin-4-one precursors derived from 5-oxo-proline and proline

Amedjkouh, Mohamed,Ahlberg, Per

, p. 2229 - 2234 (2007/10/03)

Efficient syntheses of chiral vicinal diamines derived from (S)-oxo-proline and (S)-proline are described. The novel diastereomerically pure precursor (2R,5S)-2-trichloromethyl-1-aza-3-oxabicyclo-[3.3.0]-octan-4,8-dione 3 and its enantiomer are readily available by reaction of the inexpensive enantiomers of 5-oxo-proline with chloral. Compound 3 reacts with primary and secondary amines to afford the 5-oxo-prolylamides 4 in quantitative yield. In contrast, the (S)-proline-derived precursor (2R,5S)-2-trichloromethyl-1-aza-3-oxabicyclo[3.3.0]octan-4-one 6 gave (S)-N-formylprolylamides 9 and/or (S)-prolylamides 8 depending on the reaction conditions. Upon reduction with LiAlH4, amides 4 and 9 afforded the proline-derived (S)-2-(alkylaminomethyl)pyrrolidines 1 and (S)-N-methyl-2-(alkylaminomethyl)-pyrrolidines 5 in 70-90% yields.

HIGHLY ENANTIOSELECTIVE ALDOL-TYPE REACTION OF 3-ACETYLTHIAZOLIDINE-2-THIONE WITH ACHIRAL ALDEHYDES

Iwasawa, Nobuharu,Mukaiyama, Teruaki

, p. 297 - 298 (2007/10/02)

A highly enantioselective aldol-type reaction forming various β-hydroxy carbonyl compounds from 3-acetylthiazolidine-2-thione and achiral aldehydes is achieved via divalent tin enolate employing chiral diamine derived from (S)-proline as a ligand.

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