86310-98-7Relevant articles and documents
Chiral hypervalent iodine(III) catalyst promotes highly enantioselective sulfonyl-and phosphoryl-oxylactonizations
Gelis, Coralie,Dumoulin, Audrey,Bekkaye, Mathieu,Neuville, Luc,Masson, Géraldine
, p. 278 - 281 (2017)
An efficient enantioselective hypervalent iodine promoted oxylactonization of 4-pentenoic acids has been achieved using stoichiometric or a catalytic amount of chiral aryl-λ3-iodane. This reaction provides straightforward access to a wide range of sulfonyloxy-and phosphoryloxy-γ-butyrolactones in respectable yields with moderate to excellent enantioselectivities.