866927-32-4

Basic information

• Product Name: methyl 4-O-benzyl-5,6-O-isopropylidene-D-erythro-(E)-2-hexenoate
• Synonyms: methyl 4-O-benzyl-5,6-O-isopropylidene-D-erythro-(E)-2-hexenoate
• CAS NO: 866927-32-4
• Molecular Weight: 306.359
• Mol File: 866927-32-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 4-O-benzyl-5,6-O-isopropylidene-D-erythro-(E)-2-hexenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-O-benzyl-5,6-O-isopropylidene-D-erythro-(E)-2-hexenoate(866927-32-4)
• EPA Substance Registry System: methyl 4-O-benzyl-5,6-O-isopropylidene-D-erythro-(E)-2-hexenoate(866927-32-4)

Safety Data

• Hazardous Substances Data: 866927-32-4(Hazardous Substances Data)

Upstream product

• 90-80-2 D-Glucono-1,5-lactone 
• 127530-03-4 methyl 2-deoxy-3,4;5,6-di-O-isopropylidene-D-arabino-hexonate 
• 114743-85-0 methyl 3,4:5,6-di-O-isopropylidene-D-gluconate 
• 127529-99-1 (S)-Chloro-((4R,5S,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-acetic acid methyl ester 
• 100-39-0 benzyl bromide 
• 127530-06-7 methyl E-4-<(4R)-2,2-dimethyl-1,3-dioxolan-4-yl>-4-(S)-hydroxy-but-2-enoate 

Downstream Products

• 111462-38-5 1-O-benzyl-3,4-O-isopropylidene-D-erythritol ⁽¹²⁾ and 2-O-benzyl-3,4-O-isopropylidene-D-erythritol 

Relevant articles and documents

Convenient enantiopure synthesis of (2S,3R)-2-O-benzyl-3,4-O- isopropylidene-D-erythritol from D-(+)-glucono-δ-lactone: A potential C4 chiral building block

A new convenient synthesis of (2S,3R)-2-O-benzyl-3,4-O-isopropylidene-D- erythritol has been achieved starting from extremely cheap and commercially available D-(+)-glucono-δ-lactone. It involves two carbon excisions using ozonolysis. The inbuilt stereoch