869290-47-1

Basic information

• Product Name: [[(1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methyl]diphenylphosphine oxide
• Synonyms: [[(1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methyl]diphenylphosphine oxide
• CAS NO: 869290-47-1
• Molecular Weight: 336.414
• Mol File: 869290-47-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [[(1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methyl]diphenylphosphine oxide(CAS DataBase Reference)
• NIST Chemistry Reference: [[(1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methyl]diphenylphosphine oxide(869290-47-1)
• EPA Substance Registry System: [[(1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methyl]diphenylphosphine oxide(869290-47-1)

Safety Data

• Hazardous Substances Data: 869290-47-1(Hazardous Substances Data)

Upstream product

• 19894-98-5 6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-ol 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 768402-54-6 (1S,2R,3S,5R)-2-[(diphenylphosphinoyl)methyl]-6,6-dimethylbicyclo[3.1.1]heptan-3-ol 
• 768402-63-7 (1S,2R,3S,5R)-2-[(dicyclohexylphosphinoyl)methyl]-6,6-dimethylbicyclo[3.1.1]heptan-3-ol 

Relevant articles and documents

Novel chiral diphosphine ligands with a pinene core obtained via an allylphosphinite-allylphosphine oxide rearrangement

A number of new chiral diphosphine ligands with a pinene framework were synthesized and tested in some transition metal-catalyzed asymmetric reactions (enantioselectivities up to 84% ee were achieved). The [2,3]-sigmatropic allylphosphinite-allyl phosphin