871979-80-5

Basic information

• Product Name: 1,2-Pyrrolidinedicarboxylic acid, 5-[(phenylmethoxy)methyl]-, 1-(1,1-dimethylethyl) ester, (2S,5S)-
• CAS NO: 871979-80-5
• Molecular Formula: C18H25NO5
• Molecular Weight: 335.4
• Mol File: 871979-80-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,2-Pyrrolidinedicarboxylic acid, 5-[(phenylmethoxy)methyl]-, 1-(1,1-dimethylethyl) ester, (2S,5S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Pyrrolidinedicarboxylic acid, 5-[(phenylmethoxy)methyl]-, 1-(1,1-dimethylethyl) ester, (2S,5S)-(871979-80-5)
• EPA Substance Registry System: 1,2-Pyrrolidinedicarboxylic acid, 5-[(phenylmethoxy)methyl]-, 1-(1,1-dimethylethyl) ester, (2S,5S)-(871979-80-5)

Safety Data

• Hazardous Substances Data: 871979-80-5(Hazardous Substances Data)

Upstream product

• 144978-35-8 (S)-ethyl N-tert-butoxycarbonylpyroglutamate 
• 7681-52-9 sodium hypochlorite 
• 138528-06-0 (2S,5S)-5-benzyloxymethyl-1-tert-butoxycarbonyl-2-hydroxymethylpyrrolidine 

Relevant articles and documents

Divergent total synthesis of the tricyclic marine alkaloids lepadiformine, fasicularin, and isomers of polycitorols by reagent-controlled diastereoselective reductive amination

We describe a flexible and divergent route to the pyrrolo-/pyrido[1,2-j]quinoline frameworks of tricyclic marine alkaloids via a common intermediate formed by the ester-enolate Claisen rearrangement of a cyclic amino acid allylic ester. We have synthesize

Formal total synthesis of (-)-lepadiformine

A stereocontrolled approach to the preparation of the Weinreb intermediate 3 has been developed. The important features of this approach are the creation of stereogenic centers through a cyclic amino acid ester-enolate Claisen rearrangement and the use of