87763-90-4

Basic information

• Product Name: Benzenemethanol, a-(2-bromo-2-propenyl)-
• CAS NO: 87763-90-4
• Molecular Formula: C10H11BrO
• Molecular Weight: 227.101
• Mol File: 87763-90-4.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(2-bromo-2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(2-bromo-2-propenyl)-(87763-90-4)
• EPA Substance Registry System: Benzenemethanol, a-(2-bromo-2-propenyl)-(87763-90-4)

Safety Data

• Hazardous Substances Data: 87763-90-4(Hazardous Substances Data)

Upstream product

• 936-51-6 2-phenyl-1,3-dioxolane 
• 513-31-5 2-bromoallyl bromide 
• 100-52-7 benzaldehyde 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 932-90-1 Benzaldoxime 
• 213337-22-5 1-(hydrodimethylsilyloxy)-1-phenyl-3-butyne 
• 213337-24-7 2,2-dimethyl-3-methylene-5-phenyl-1-oxa-2-silacyclopentane 
• 138416-08-7 (2-bromoallyl)diphenoxyborane 

Downstream Products

• 26613-71-8 4-phenyl-2-methylenebutyrolactone 
• 265671-59-8 (3-bromo-1-phenylbut-3-enyloxy)diphenyl(trimethylsilyl)silane 

Relevant articles and documents

Intermolecular Diels-Alder Cycloaddition/Cross-Coupling Sequences of 2-Bromo-1,3-butadienes

2-Bromo-1,3-butadienes are demonstrated to be effective substrates for tandem Diels-Alder/transition metal cross-coupling reaction sequences. Intermolecular cycloaddition of a 2-bromo-1,3-diene with activated dienophiles proceeded under Lewis acid catalys

A Copper Catalyst with a Cinchona-Alkaloid-Based Sulfonamide Ligand for Asymmetric Radical Oxytrifluoromethylation of Alkenyl Oximes

A copper-catalyzed asymmetric radical oxytrifluoromethylation of alkenyl oxime and Togni's reagent has been successfully developed, thereby providing straightforward access to CF3-containing isoxazolines bearing α-tertiary stereocenters with excellent yield and enantioselectivity. The key to success is the rational design of cinchona-alkaloid-based sulfonamides as neutral/anionic hybrid ligands to effectively control the stereochemistry in copper-catalyzed reactions involving free alkyl radical species. The utility of this method is illustrated by efficient transformation of the products into useful chiral CF3-containing 1,3-aminoalcohols.

TMSBr/InBr3-promoted Prins cyclization/homobromination of dienyl alcohol with aldehyde to construct cis-THP containing an exocyclic E-alkene

A TMSBr/InBr3-promoted Prins cyclization/homobromination reaction of dienyl alcohol with aldehyde has been developed to construct a unique cis-E THP shown as the A ring in (-)-exiguolide and the B ring in bryostatins.