87876-84-4

Basic information

• Product Name: (E)-acetophenone-O-ethoxycarbonyloxime
• Synonyms: (E)-acetophenone-O-ethoxycarbonyloxime
• CAS NO: 87876-84-4
• Molecular Weight: 207.229
• Mol File: 87876-84-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-acetophenone-O-ethoxycarbonyloxime(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-acetophenone-O-ethoxycarbonyloxime(87876-84-4)
• EPA Substance Registry System: (E)-acetophenone-O-ethoxycarbonyloxime(87876-84-4)

Safety Data

• Hazardous Substances Data: 87876-84-4(Hazardous Substances Data)

Upstream product

• 53009-69-1 Benzoylacetaldoxim 
• 1441409-96-6 (E)-ethyl 2-cyano-2-(2-nitrophenylsulfonyloxyimino)acetate 
• 10341-75-0 (E)-1-phenylethanone oxime 
• 541-41-3 chloroformic acid ethyl ester 

Downstream Products

• 103-84-4 Acetanilid 
• 59073-51-7 N-Phenyl-thioacetimidic acid ethyl ester 
• 87876-88-8 N-Phenyl-acetimidoyl iodide 
• 779-54-4 phenyl(1-phenylethyl)amine 
• 37857-41-3 N-(1'-methyl-2'-butenyl)aniline 
• 58008-18-7 N-(1,2,2-Trimethyl)propylanilin 

Relevant articles and documents

Improved procedures for the Beckmann rearrangement: The reaction of ketoxime carbonates with boron trifluoride etherate

A variety of ketoxime ethyl carbonates-easily prepared from the oximes and ethyl chloroformate-undergo the Beckmann rearrangement upon treatment with 1 equivalent of boron trifluoride etherate, in dichloromethane solution at room temperature in excellent yields (generally 75-99%). (C) 2000 Elsevier Science Ltd.