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CAS

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88196-67-2

(1R,2R)-1,2-Dimethylbutylamin is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 88196-67-2 Structure

  • Basic information

    1. Product Name: (1R,2R)-1,2-Dimethylbutylamin
    2. Synonyms: (1R,2R)-1,2-Dimethylbutylamin
    3. CAS NO:88196-67-2
    4. Molecular Formula:
    5. Molecular Weight: 101.192
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 88196-67-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (1R,2R)-1,2-Dimethylbutylamin(CAS DataBase Reference)
    10. NIST Chemistry Reference: (1R,2R)-1,2-Dimethylbutylamin(88196-67-2)
    11. EPA Substance Registry System: (1R,2R)-1,2-Dimethylbutylamin(88196-67-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 88196-67-2(Hazardous Substances Data)

88196-67-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 88196-67-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,8,1,9 and 6 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 88196-67:
(7*8)+(6*8)+(5*1)+(4*9)+(3*6)+(2*6)+(1*7)=182
182 % 10 = 2
So 88196-67-2 is a valid CAS Registry Number.

88196-67-2Downstream Products

88196-67-2Relevant articles and documents

Stereochemistry of Aliphatic Carbocations, 12. Alkyl Shifts between Secondary Carbon Atoms

Kirmse, Wolfgang,Prolingheuer, Ernst-Christoph

, p. 104 - 128 (2007/10/02)

Several optically active, β-branched alkylamines have been synthesized from amino acids.The corresponding amines were obtained from isobutyraldehyde and 2-methylbutanal (37), respectively.The stereochemistry at the terminus of 1,2-methyl shifts has been elucidated in the nitrous acid deaminations of 4 and 21.Predominant, although incomplete inversion at the migration terminus is consistent with conformational control rather than neighboring group participation.The deamination of 31 involves a degenerate 1,2-ethyl shift and a nondegenerate 1,2-methyl shift, the reverse holds for 44.Complete inversion at the origin of the methyl migrations and the absence of subsequent retrogressive H shifts strongly support the intermediacy of methyl-bridged carbocations.Partial racemization at the origin of the ethyl migrations has been traced to proton shifts within ethyl-bridged intermediates.Rearranged open cations contribute significantly to the overall reaction if micelles are produced by self-aggregation of the alkylammonium ions.

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