884-36-6Relevant articles and documents
Ni-Catalyzed Carboxylation of Unactivated Alkyl Chlorides with CO2
B?rjesson, Marino,Moragas, Toni,Martin, Ruben
supporting information, p. 7504 - 7507 (2016/07/06)
A catalytic carboxylation of unactivated primary, secondary, and tertiary alkyl chlorides with CO2 at atmospheric pressure is described. This protocol represents the first intermolecular cross-electrophile coupling of unactivated alkyl chlorides, thus leading to new knowledge in the cross-coupling arena.
Functionalization of Saturated Hydrocarbons. 14. Further Studies on the Mechanism of Gif-Type Systems
Barton, Derek H. R.,Halley, Frank,Ozbalik, Nubar,Schmitt, Martine,Young, Esme,Balavoine, Gilbert
, p. 7144 - 7149 (2007/10/02)
The photolysis (W light) of acyl derivatives of N-hydroxy-2-thiopyridone in pyridine-acetic acid permits a study of the partioning of secondary radicals between oxygen, pyridine, and the thione function.Comparison with the GifIV oxidation system for saturated hydrocarbons confirms that radicals are not involved in oxidation at secondary positions.On the contrary, radical behavior at the tertiary position in adamantane is again established.The two recently introduced Gif-type systems, GoAggI and GoAggII, have been shown to give the same overall selectivity in attack on adamantane with the usual coupling of the tertiary radical with pyridine.
Oxy-Cope Rearrangement Route to Bridgehead Olefins
Levine, Samuel G.,McDaniel, Roger L.
, p. 2199 - 2200 (2007/10/02)
Bicyclic bridgehead olefins, with a carbonyl group included in the largest bridge, may be synthesized by oxy-Cope rearrangement of easily accessible spirocyclic precursors.
