88876-19-1Relevant articles and documents
Sodium Perborate: A Facile Catalyst for Allylation of Active Centers
Jayaprakash, Soora Harinath,Krishna, Balam Satheesh,Prasad, Sthanikam Siva,Sudha, Sarva Santhi,Reddy, Cirandur Suresh
supporting information, p. 355 - 362 (2015/10/29)
An efficient and ecofriendly allylation of O-H, N-H, and C-H groups has been achieved successfully with the reaction of allyl bromide by using sodium perborate as a new catalyst in aqueous media. The advantage of this method is operationally simple, short reaction time, good yield, and simple workup conditions over the previously reported conventional methods such as amination, oxyalkylation reactions of allyl bromide, and Friedel-Crafts allylation chemistry.
The Pyrolysis of N-Allyl Compounds: Free-radical and Retro-ene Mechanisms
Cadogan, J. I. G.,Hickson, Clare L.,McNab, Hamish
, p. 2247 - 2273 (2007/10/02)
Flash vacuum pyrolysis of N-alkyl-N-allylanilines gives imines by free radical cleavage of the allyl group followed by loss of an atom (or group of atoms) from the α-carbon atom of the alkyl group.The corresponding N-propargyl derivatives also give imines on pyrolysis, but the mechanism is a concerted retro-ene process which may lead to different products from the corresponding N-allyl compound.N-Allyl-N,N-dialkylamines also decompose thermally by a retro-ene process
