89616-40-0

Basic information

• Product Name: BENZYL GLYCIDYL ETHER
• Synonyms: 2-(BENZYLOXYMETHYL)OXIRANE;1-BENZYLOXY-2,3-EPOXYPROPANE;BENZYL GLYCIDYL ETHER;VITAS-BB TBB000194;3-BENZYLOXY-1,2-EPOXYPROPANE;Benzyl glycidol ether;Benzyl glycidyl ether ,99%;692 (Benzyl Glycidyl Ether)
• CAS NO: 89616-40-0
• Molecular Formula: C₁₀H₁₂O₂
• Molecular Weight: 164.2
• EINECS: 220-899-5
• Mol File: 89616-40-0.mol
• Article Data: 59

Chemical Properties

• Boiling Point: 70-73 °C11 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.077 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.5170(lit.)
• CAS DataBase Reference: BENZYL GLYCIDYL ETHER(CAS DataBase Reference)
• NIST Chemistry Reference: BENZYL GLYCIDYL ETHER(89616-40-0)
• EPA Substance Registry System: BENZYL GLYCIDYL ETHER(89616-40-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 89616-40-0(Hazardous Substances Data)

Usage

General Description

Benzyl glycidyl ether is a chemical compound with the formula C10H12O2. It is a colorless liquid with a slightly sweet odor and is commonly used as a reactive diluent in epoxy resins. Benzyl glycidyl ether is also used as a synthesis intermediate in the production of various chemical compounds, such as fragrances, pharmaceuticals, and biocides. It is important to handle this chemical with caution as it can cause skin and eye irritation, and it may also be harmful if inhaled or ingested. Benzyl glycidyl ether should be stored and used in a well-ventilated area, and protective equipment such as gloves and safety goggles should be worn when handling this substance.

InChI:InChI=1S/C10H12O2/c1-2-4-9(5-3-1)6-11-7-10-8-12-10/h1-5,10H,6-8H2

Upstream product

• 14593-43-2 benzyl allyl ether 
• 56552-80-8 (R)-3-benzyloxy-1,2-propanediol 
• 17325-85-8 (2S)-3-(benzyloxy)propane-1,2-diol 
• 100-39-0 benzyl bromide 
• 78906-15-7 tert-butyldimethylsilyl (S)-glycidyl ether 
• 112497-11-7 (R)-1-Benzyloxy-3-p-tolylsulfanyl-propan-2-ol 
• 57044-25-4 (R)-oxiranemethanol 
• 2930-05-4 Benzyloxymethyl-oxiran 
• 100-51-6 benzyl alcohol 
• 128572-85-0 2-acetoxy-1-(benzyloxy)-3-chloropropane 
• 1122091-57-9 C₁₈H₂₂O₅S 
• 67843-74-7 (S)-epichlorohydrin 
• 124-38-9 carbon dioxide 
• 62-53-3 aniline 

Downstream Products

• 125782-68-5 (S)-1-Benzyloxy-3-(5-hydroxymethyl-furan-2-yl)-propan-2-ol 
• 85758-01-6 (R)-5-Benzyloxy-4-hydroxy-2-p-tolyl-pentanenitrile 
• 145308-75-4 (S)-1-benzyloxy-4-decyn-2-ol 
• 81309-78-6 (R)-5-Benzyloxy-2-(3,4-dimethoxy-phenyl)-4-hydroxy-pentanenitrile 
• 139242-76-5 (2S)-1-(Phenylmethoxy)-4-(phenylsulfonyl)-5-(trimethylsilyl)-2-pentanol 
• 150620-97-6 (S)-1-O-Benzylnonane-1,2-diol 
• 130052-46-9 (2'R)-1-O-(2'-methoxyhexadecyl)-3-O-benzyl-sn-glycerol 
• 130052-40-3 (2'S)-1-O-(2'-methoxyhexadecyl)-3-O-benzyl-sn-glycerol 
• 117039-90-4 (2S)-1-benzyloxy-2-butanol 
• 145229-56-7 (2R,6S)-1,7-Bis-benzyloxy-hept-3-yne-2,6-diol 
• 117821-04-2 (R)-4-Benzyloxy-3-hydroxybutyl methyl sulfoxide 
• 107696-75-3 (3S,5S)-5-Benzyloxymethyl-3-methyl-dihydro-furan-2-one 
• 107696-75-3 (3R,5S)-5-Benzyloxymethyl-3-methyl-dihydro-furan-2-one 
• 130052-32-3 (R)-1-benzyloxy-2-methoxyhexadecane 

Relevant articles and documents

Diastereoselective Alkene Hydroesterification Enabling the Synthesis of Chiral Fused Bicyclic Lactones

Palladium-catalysed diastereoselective hydroesterification of alkenes assisted by the coordinative hydroxyl group in the substrate afforded a variety of chiral γ-butyrolactones bearing two stereocenters. Employing the carbonylation-lactonization products as the key intermediates, the route from the alkenes with single chiral center to chiral THF-fused bicyclic γ-lactones containing three stereocenters was developed.

Stereoselective total synthesis of (?)-galantinic acid and 1-deoxy-5-hydroxysphingolipids via prins cyclization

The stereoselective total synthesis of (?)-galantinic acid 1 and 1-deoxy-5-hydroxysphingolipids 4 is described via Prins cyclization protocol followed by reductive ring opening sequence of substituted pyrenol derivative 6. The target molecules were synthesized using a common synthetic intermediate epoxide 5. Besides, we also proposed synthetic pathways to achieve other structural analogues using common intermediates.

Chiral Bifunctional Metalloporphyrin Catalysts for Kinetic Resolution of Epoxides with Carbon Dioxide

Chiral binaphthyl-strapped Zn(II) porphyrins with triazolium halide units were synthesized as bifunctional catalysts for kinetic resolution of epoxides with CO2. Several catalysts were screened by changing the linker length and nucleophilic counteranions, and the optimized catalyst accelerated the enantioselective reaction at ambient temperature to produce optically active cyclic carbonates and epoxides.