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909122-63-0

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909122-63-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 909122-63-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,0,9,1,2 and 2 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 909122-63:
(8*9)+(7*0)+(6*9)+(5*1)+(4*2)+(3*2)+(2*6)+(1*3)=160
160 % 10 = 0
So 909122-63-0 is a valid CAS Registry Number.

909122-63-0Downstream Products

909122-63-0Relevant articles and documents

Single-Handed Helical Poly(quinoxaline-2,3-diyl)s Bearing Achiral 4-Aminopyrid-3-yl Pendants as Highly Enantioselective, Reusable Chiral Nucleophilic Organocatalysts in the Steglich Reaction

Yamamoto, Takeshi,Murakami, Ryo,Suginome, Michinori

supporting information, p. 2557 - 2560 (2017/03/01)

Helically chiral poly(quinoxaline-2,3-diyl)s bearing 4-aminopyrid-3-yl pendants were synthesized as new helical-polymer-based chiral nucleophilic organocatalysts. The obtained chiral nucleophilic polymer catalysts exhibited high catalytic activity, enantioselectivity, and reusability in asymmetric Steglich rearrangement of oxazolyl carbonate to C-carboxyazlactone. The polyquinoxaline-based, helically chiral DMAP catalyst mediated intramolecular acyl transfer selectively, by contrast with known small-molecule-based chiral organocatalysts, which also mediate intermolecular acyl transfers.

Catalytic enantioselective Steglich rearrangements using chiral N-heterocyclic carbenes

Campbell, Craig D.,Concellon, Carmen,Smith, Andrew D.

scheme or table, p. 797 - 811 (2011/08/06)

The evaluation of a range of enantiomerically pure NHCs, prepared in situ from imidazolinium or triazolium salt precatalysts, to promote the catalytic enantioselective Steglich rearrangement of oxazolyl carbonates to their C-carboxyazlactones, is reported. Modest levels of enantioselectivity (up to 66% ee) are observed using oxazolidinone derived NHCs.

Probing the efficiency of N-heterocyclic carbene promoted O- to C-carboxyl transfer of oxazolyl carbonates

Thomson, Jennifer E.,Campbell, Craig D.,Concellon, Carmen,Duguet, Nicolas,Rix, Kathryn,Slawin, Alexandra M. Z.,Smith, Andrew D.

, p. 2784 - 2791 (2008/09/20)

(Chemical Equation Presented) Screening of a range of azolium salts, bases and solvents for reactivity indicates that triazolinylidenes, generated in situ with KHMDS in THF, promote the Steglich rearrangement of oxazolyl carbonates with high catalytic efficiency (typical reaction time 5 min at 1.5 mol % NHC). This protocol shows wide substrate applicability, even allowing the efficient generation of vicinal quaternary centers. An improved experimental procedure is also described that allows a simplified one-pot reaction protocol to be employed with similarly high catalytic efficiency.

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