914311-44-7

Basic information

• Product Name: 2-bromo-6-fluorobenzaldehyde hydrazone
• Synonyms: 2-bromo-6-fluorobenzaldehyde hydrazone
• CAS NO: 914311-44-7
• Molecular Weight: 217.04
• Mol File: 914311-44-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-bromo-6-fluorobenzaldehyde hydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-6-fluorobenzaldehyde hydrazone(914311-44-7)
• EPA Substance Registry System: 2-bromo-6-fluorobenzaldehyde hydrazone(914311-44-7)

Safety Data

• Hazardous Substances Data: 914311-44-7(Hazardous Substances Data)

Upstream product

• 360575-28-6 2-bromo-6-fluorobenzaldehyde 

Downstream Products

• 1422-54-4 1-bromo-3-fluoro-2-methyl-benzene 
• 186407-74-9 4-bromoindazole 
• 914311-46-9 1-benzyl-4-bromoindazole 
• 952734-38-2 2-benzyl-4-bromo-2H-indazole 

Relevant articles and documents

New practical synthesis of indazoles via condensation of o-fluorobenzaldehydes and their O-methyloximes with hydrazine

The reaction of o-fluorobenzaldehydes and their O-methyloximes with hydrazine has been developed as a new practical synthesis of indazoles. Utilization of the methyloxime derivatives of benzaldehydes (in the form of the major E-isomers) in this condensation effectively eliminated a competitive Wolf-Kishner reduction to fluorotoluenes, which was observed in the direct preparations of indazoles from aldehydes. Reaction of Z-isomers of methyloximes with hydrazine resulted in the formation of 3-aminoindazoles via a benzonitrile intermediate.