91899-35-3

Basic information

• Product Name: (E)-(dodec-2-enyl)trimethylsilane
• Synonyms: (E)-(dodec-2-enyl)trimethylsilane
• CAS NO: 91899-35-3
• Molecular Weight: 240.505
• Mol File: 91899-35-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-(dodec-2-enyl)trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(dodec-2-enyl)trimethylsilane(91899-35-3)
• EPA Substance Registry System: (E)-(dodec-2-enyl)trimethylsilane(91899-35-3)

Safety Data

• Hazardous Substances Data: 91899-35-3(Hazardous Substances Data)

Upstream product

• 70875-30-8 (Z)-1-(trimethylsilyl)dodec-1-ene 

Downstream Products

• 4048-42-4 1-dodecen-3-ol 
• 22104-81-0 (2E)-dodec-2-en-1-ol 

Relevant articles and documents

Platinum-catalyzed allylation of carbon electrophiles with alkenylsilanes

In the presence of catalytic amounts of PtCl2 and AgSbF6, (Z)-alkenylsilanes react with various carbon electrophiles at the γ-position to give allylation products. A plausible mechanism for the Pt-catalyzed allylation involves alkene migration of alkenylsilanes to allylsilanes and subsequent allylation of carbon electrophiles.