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92557-51-2

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92557-51-2 Usage

General Description

1H-Indole-3-methanol, 5-bromo- is a chemical compound with a molecular formula C9H8BrNO. It is a brominated derivative of 1H-indole-3-methanol, which is a naturally occurring compound found in certain plants and fungi. The addition of a bromine atom to the molecule changes its properties, potentially affecting its reactivity and bioavailability. 1H-Indole-3-methanol, 5-bromo- may have potential applications in pharmaceuticals, agrochemicals, and other industries due to its unique structure and potential biological activities. Further research is needed to fully understand its potential uses and effects.

Check Digit Verification of cas no

The CAS Registry Mumber 92557-51-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,2,5,5 and 7 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 92557-51:
(7*9)+(6*2)+(5*5)+(4*5)+(3*7)+(2*5)+(1*1)=152
152 % 10 = 2
So 92557-51-2 is a valid CAS Registry Number.

92557-51-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name (5-Bromo-1H-indol-3-yl)methanol

1.2 Other means of identification

Product number -
Other names 5-Bromo-indole-3-carbinol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:92557-51-2 SDS

92557-51-2Relevant articles and documents

Oxidized graphitic carbon nitride as a sustainable metal-free catalyst for hydrogen transfer reactions under mild conditions

Bahuguna, Ashish,Choudhary, Priyanka,Dhankhar, Sandeep Singh,Krishnan, Venkata,Kumar, Ajay,Nagaraja, C. M.

, p. 5084 - 5095 (2020/08/25)

The development of green and sustainable transfer hydrogenation protocols without the use of expensive noble metals and toxic solvents is a challenging task. Herein, a highly stable, low-cost, metal-free heterogeneous catalyst, oxidized graphitic carbon nitride (O-GCN), has been developed, which exhibits efficient catalytic hydrogen transfer reactions of carbonyl compounds to corresponding alcohols under mild reaction conditions. The heterogeneous catalyst was synthesized by the chemical oxidation of graphitic carbon nitride (GCN) nanosheets, which results in the generation of carboxyl, hydroxyl and ketone groups over the GCN surface. These hydrophilic groups functionalized on the surface of O-GCN nanosheets act as catalytically active sites for the hydrogen transfer reactions of carbonyl compounds. A wide range of substrates was investigated for the hydrogen transfer reactions using 2-propanol both as a hydrogen donor and a solvent. The O-GCN nanosheets resulted in high yields and high turnover numbers (TON) demonstrating the versatile catalytic potential of the as-synthesized catalyst. The detailed optimization of the reaction parameters (temperature, time and catalyst amount) was performed, in addition to the calculation of green metric parameters. Moreover, the catalyst could be easily recovered and was used for five runs without any significant loss in catalytic activity. This study provides a green, sustainable, attractive, and useful methodology for the hydrogen transfer reactions of a wide range of carbonyl compounds.

Regioselective hydroarylation reactions of C3 electrophilic N-acetylindoles activated by FeCl3: An entry to 3-(Hetero)arylindolines

Beaud, Rodolphe,Guillot, Regis,Kouklovsky, Cyrille,Vincent, Guillaume

supporting information, p. 7492 - 7500 (2014/06/23)

A method for the direct and rare umpolung of the 3 position of indoles is reported. The activation of N-acetylindole with iron(III) chloride allows the C-H addition of aromatic and heteroaromatic substrates to the C2-C3 double bond of the indole nucleus to generate a quaternary center at C3 and leads regioselectively to 3-arylindolines. Optimization, scope (50 examples), practicability (gram scale, air atmosphere, room temperature), and mechanistic insights of this process are presented. Synthetic transformations of the indoline products into drug-like compounds are also described.

Analogs of indole-3-carbinol metabolites as chemotherapeutic and chemopreventive agents

-

Page/Page column 19, (2008/06/13)

Novel compounds useful as chemotherapeutic and chemopreventive agents are provided. The compounds are analogs of indole-3-carbinol metabolites wherein the structures and substituents of the compounds are selected to enhance the compounds' overall efficacy, particularly with respect to therapeutic activity, oral bioavailability, long-term safety, patient tolerability, and therapeutic window. The compounds are useful not only in treatment of cancer but also in prevention of cancer. One preferred class of the novel compounds have the structure of formula (I) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, and R12 are defined herein. Pharmaceutical compositions are provided as well, as are methods of synthesis and use.

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