927-77-5

Basic information

• Product Name: N-PROPYLMAGNESIUM BROMIDE
• Synonyms: N-PROPYLMAGNESIUM BROMIDE: 27% (2M) IN TETRAHYDROFURAN;2MOL/L PROPYLMAGNESIUM BROMIDE TETRAHYDROFURAN SOLUTION;Propylmagnesium Bromide (27% in Tetrahydrofuran, ca. 2mol/L);Propylbromomagnesium;Propylmagnesium Bromide (ca. 27% in Tetrahydrofuran, ca. 2mol/L);magnesium propane bromide;Propylmagnesium bromide [2 M solution in THF];(ca. 27% in Tetrahydrofuran, ca. 2Mol/L)
• CAS NO: 927-77-5
• Molecular Formula: C₃H₇BrMg
• Molecular Weight: 147.3
• EINECS: 213-162-4
• Product Categories: Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Grignard Reagent
• Mol File: 927-77-5.mol
• Article Data: 15

Chemical Properties

• Melting Point: 61.5-62.5℃
• Boiling Point: 120-121 °C(Press: 0.2 Torr)
• Flash Point: -17°C (THF)
• Appearance: /
• Density: 1,058 g/cm3
• CAS DataBase Reference: N-PROPYLMAGNESIUM BROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-PROPYLMAGNESIUM BROMIDE(927-77-5)
• EPA Substance Registry System: N-PROPYLMAGNESIUM BROMIDE(927-77-5)

Safety Data

• Statements: 11-15-19-34-37-36/37/38-14
• Safety Statements: 7/8-26-36/37/39-43-16
• RIDADR: 3399
• HazardClass: 4.3/3
• PackingGroup: I
• Hazardous Substances Data: 927-77-5(Hazardous Substances Data)

Usage

Chemical Properties

Colorless to yellow or brownn liquid

Uses

Alkylating agent in organic synthesis.

Definition

Available as a solution in ether; a Grignard reagent.

InChI:InChI=1/C3H7.BrH.Mg/c1-3-2;;/h1,3H2,2H3;1H;/q;;+1/p-1/rC3H7BrMg/c1-2-3-5-4/h2-3H2,1H3

Upstream product

• 106-94-5 propyl bromide 

Downstream Products

• 111-27-3 hexan-1-ol 
• 13154-22-8 chloro-methyl-propyl-silane 
• 999-03-1 methyldipropylsilane 
• 64986-16-9 meso-5,6-diphenyl-decane 
• 4166-46-5 2,3-dimethyl-hexan-3-ol 
• 6220-95-7 N-4-Heptylpiperidine 
• 123-72-8 butyraldehyde 
• 22971-32-0 1-(pyridin-2-yl)butan-1-one 
• 1701-70-8 1-pyridin-3-yl-butan-1-one 
• 107-10-8 propylamine 
• 142-84-7 di-n-propylamine 
• 107-87-9 2-Pentanone 
• 995-24-4 me(1-pr)3Si 
• 994-63-8 Ethyl-tripropylsilan 

Relevant articles and documents

4-Alkyl-3-azidomethyl-2-ethoxy-2,5-dihydro-5 H-1,2-oxaphosphole 2-Oxides: Synthesis and 1,3-Cycloaddition

Starting from phosphorylated allenes, a three-steps synthesis of a new class of organic azides with a 1,2-oxaphospholene carbon skeleton has been developed. The series of obtained 4-alkyl-3-azidomethyl-2-ethoxy-2,5-dihydro-5H-1,2-oxaphosphole 2-oxides were utilized in the 1,3-cycloaddition with alkyl 2-[1-(propyn-2-yl)-1H-indol-3-yl]-2-oxoacetates for the synthesis of conjugates, which are potentially active cytostatics.

Method for producing alkyl-bridged ligand systems and transition metal compounds

The invention relates to a method for producing highly substituted alkyl-bridged ligand systems on the basis of indene derivatives and transition metal compounds. Said alkyl-bridged ligand systems can be obtained in high yields using this method.

19-nor-pregnene derivatives and pharmaceuticals containing such derivatives

The invention relates to compounds of the formula:in which R1, R2, R3, R4, R5, R6, n and X are as defined in the specification, and to pharmaceutical compositions containing them.These compounds are excellent progestogens which are devoid of residual androgenic activity.