928-97-2

Basic information

• Product Name: TRANS-3-HEXEN-1-OL
• Synonyms: (3E)-Hexenol;(e)-3-hexen-1-o;(E)-3-Hexen-1-ol;(E)-Hex-3-en-1-ol;(E)Hex-3-enol;3(E)-hexen-1-ol;3-hexen-1-0l;E-3-Hexenol
• CAS NO: 928-97-2
• Molecular Formula: C₆H₁₂O
• Molecular Weight: 100.16
• EINECS: 213-193-3
• Product Categories: Acyclic;Alkenes;Building Blocks;Chemical Synthesis;Organic Building Blocks
• Mol File: 928-97-2.mol
• Article Data: 50

Chemical Properties

• Melting Point: 99℃
• Boiling Point: 61-62 °C12 mm Hg(lit.)
• Flash Point: 138 °F
• Appearance: colourless liquid
• Density: 0.817 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.439(lit.)
• Storage Temp.: Refrigerator
• Solubility: Chloroform (Sparingly), Methanol (Slightly)
• PKA: 15.00±0.10(Predicted)
• Water Solubility: Slightly soluble in water.
• Stability: Stable. Combustible. Incompatible with strong oxidizing agents, strong acids.
• Merck: 14,4700
• BRN: 1719713
• CAS DataBase Reference: TRANS-3-HEXEN-1-OL(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-3-HEXEN-1-OL(928-97-2)
• EPA Substance Registry System: TRANS-3-HEXEN-1-OL(928-97-2)

Safety Data

• Hazard Codes: Xi
• Statements: 10-36
• Safety Statements: 23-24/25-26
• RIDADR: UN 1987 3/PG 3
• WGK Germany: 3
• TSCA: Yes
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 928-97-2(Hazardous Substances Data)

Usage

Chemical Properties

Different sources of media describe the Chemical Properties of 928-97-2 differently. You can refer to the following data:
1. colourless liquid
2. Colorless liquid; grassy green aroma

Occurrence

Reported to be found in Plectranthus glandulosus Hook. f. leaf oil Cameroon (1.20%), laurel leaf oil Turkey (0.10%), and jasmine absolute China (0.05%).

Uses

trans-3-Hexen-1-ol stimulates the antennae of male H. cunea moths. It is also used as an organic chemical synthesis intermediate.

Aroma threshold values

Green type, high strength odor; recommend smelling in a 1.00% solution or less

General Description

trans-3-Hexen-1-ol (trans 3-Hexenol) stimulates the antennae of male H. cunea moths.

InChI:InChI=1S/C6H12O/c1-2-3-4-5-6-7/h3-4,7H,2,5-6H2,1H3/b4-3+

Upstream product

• 1002-28-4 3-hexyn-1-ol 
• 55230-25-6 6-methyl-3,6-dihydro-2H-pyran 
• 63826-59-5 5-methyl-2-thiophenemethanol 
• 50-00-0 formaldehyd 
• 109-67-1 1-penten 
• 74379-24-1 2-hydroxymethyl-5-methyl-2,5-dihydrothiophene 
• 111-28-4 2,4-hexadiene-1-ol 
• 177859-14-2 1-(1-Ethyl-allyloxymethyl)-1H-benzotriazole 
• 110-88-3 1,3,5-Trioxan 
• 13894-61-6 methyl (E)-hex-3-enoate 
• 26553-46-8 ethyl (E)-3-hexenoate 
• 928-96-1 (Z)-3-Hexen-1-ol 
• 2396-78-3 methyl 3-hexenoate 
• 4219-24-3 hex-3-enoic acid 

Downstream Products

• 68133-76-6 (E)-hex-3-en-1-yl 2-oxopropanoate 
• 82583-54-8 2-acetoxy-2-(phenylthio)-acetic acid ethyl ester 
• 134277-88-6 [((E)-Hex-3-enyl)oxy]-phenylsulfanyl-acetic acid ethyl ester 
• 127299-58-5 (3R,4R)-3,4-Bis-benzyloxy-1-((E)-hex-3-enyl)-pyrrolidine-2,5-dione 
• 21019-60-3 (Z)-4-methyl-3-hexen-1-ol 
• 58927-81-4 (+/-)-(4E)-4-hepten-2-ol 
• 63714-11-4 trans-4-methyl-3-hexen-1-ol 
• 118759-60-7 2-((2S,3R)-3-ethyloxiran-2-yl)ethan-1-ol 
• 67663-02-9 2-(3-ethyloxiran-2-yl)ethan-1-ol 
• 67393-83-3 2-((2RS,3RS)-3-ethyloxiran-2-yl)ethan-1-ol 
• 3681-82-1 acetic acid hex-3-enyl ester 
• 60470-33-9 (E)-hex-3-en-1-yl 4-methylbenzenesulfonate 
• 433732-83-3 1,1-dimethylethyl (E)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate 
• 118759-61-8 2-((2S,3S)-3-ethyloxiran-2-yl)ethanol 

Relevant articles and documents

Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes

The Co-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes were realized by a ligand-controlled strategy. The remote hydroboration with dcype provided borylethers, while xantphos favored the formation of silyl enol ethers.

MIXTURE OF 3-HEXEN-1-OL ISOMERS AND A PROCESS OF PREPARING SAME

Compositions comprising 3-hexen-l-ol are described herein, as well as odor-imparting formulations comprising same and articles-of-manufacturing comprising such compositions or odor-imparting formulations. The compositions comprise trans- 3-hexen-l-ol in a range of from 67 % to 82 % by weight and cA-3-hexen-l-ol in a range of from 18 % to 33 % by weight, wherein a total concentration of trans- 3-hexen-l-ol and cA-3-hexen-l-ol is at least 97 % by weight. Further described herein is a process for preparing a composition comprising 3-hexen-l-ol, the process comprising: contacting 1-pentene with a formaldehyde in the presence of a Lewis acid to thereby obtain a crude mixture comprising 3-hexen-l-ol; and contacting the mixture comprising 3-hexen- l-ol with a base.

Tandem IBX-Promoted Primary Alcohol Oxidation/Opening of Intermediate β,γ-Diolcarbonate Aldehydes to (E)-γ-Hydroxy-α,β-enals

A tandem IBX-promoted oxidation of primary alcohol to aldehyde and opening of intermediate β,γ-diolcarbonate aldehyde to (E)-γ-hydroxy-α,β-enal has been developed. Remarkably, the carbonate opening delivered exclusively (E)-olefin and no over-oxidation of γ-hydroxy was observed. The method developed has been extended to complete the stereoselective total synthesis of both (S)- and (R)-coriolides and d-xylo- and d-arabino-C-20 guggultetrols.