93215-51-1

Basic information

• Product Name: Silane, [[1-(1,1-dimethylethoxy)ethenyl]oxy]trimethyl-
• CAS NO: 93215-51-1
• Molecular Formula: C9H20O2Si
• Molecular Weight: 188.342
• Mol File: 93215-51-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, [[1-(1,1-dimethylethoxy)ethenyl]oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[1-(1,1-dimethylethoxy)ethenyl]oxy]trimethyl-(93215-51-1)
• EPA Substance Registry System: Silane, [[1-(1,1-dimethylethoxy)ethenyl]oxy]trimethyl-(93215-51-1)

Safety Data

• Hazardous Substances Data: 93215-51-1(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 540-88-5 acetic acid tert-butyl ester 

Downstream Products

• 109-09-1 2-chloropyridine 
• 372-48-5 2-fluoropyridine 
• 150059-62-4 tert-butyl 2-(pyridin-2-yl)acetate 
• 146937-36-2 tert-butyl (3R,αS)-3-[N-(α-methylbenzyl)amino]-3-phenylpropanoate 
• 142466-74-8 trans-3-benzyloxycarbonylamino-4-t-butyloxycarbonylmethyl-2-azetidinone 
• 74365-82-5 (2S,4R)-(+)-2-methyl-4-tert-butylcyclohexanone 
• 74365-81-4 (2R,4R)-(+)-2-methyl-4-tert-butylcyclohexanone 
• 85048-49-3 (2R,4R)-4-tert-Butyl-2-methyl-1-prop-2-en-(Z)-ylidene-cyclohexane 
• 85048-49-3 (Z,2S,4R)-(+)-(2-methyl-4-tert-butylcyclohexylidene)propene 
• 1009733-56-5 [(2R,4R)-4-tert-Butyl-2-methyl-cyclohex-(Z)-ylidene]-acetaldehyde 
• 85048-48-2 (Z,2S,4R)-(+)-(2-methyl-4-tert-butylcyclohexylidene)acetaldehyde 
• 85048-51-7 (E,2S,4R)-(+)-(2-methyl-4-tert-butylcyclohexylidene)acetaldehyde 
• 85048-54-0 (E,2R,4R)-(+)-(2-methyl-4-tert-butylcyclohexylidene)acetaldehyde 
• 85048-47-1 2-[(2R,4R)-4-tert-Butyl-2-methyl-cyclohex-(Z)-ylidene]-ethanol 

Relevant articles and documents

Synthesis of phototrappable shape-shifting molecules for adaptive guest binding

We have designed and synthesized oligosubstituted bullvalenes 1 and 2 as adaptive molecules that can change their shapes in order to bind tightly to a suitable guest. By incorporation of a photolabile o-nitroveratryloxycarbonate (NVOC) group into bullvalenes 1 and 2, tightly binding species can be selectively isolated from a population of hundreds of interconverting structural isomers. Spontaneous strain-assisted Cope rearrangements allow these shape-shifting molecules to exist in a dynamic equilibrium of configurationally distinct valence isomers, as revealed by dynamic NMR and HPLC studies. When NVOC bullvalenes 1 and 2 were exposed to UV light, the cleavage of the NVOC group resulted in a mixture of static isomers of the corresponding bullvalone. Binding studies of NVOC bisporphyrin bullvalene 1 demonstrated that the dynamic isomeric equilibrium shifted in the presence of C60, favoring configurations with more favorable binding affinities. Irradiation of a mixture of 1 and C60 with UV light and isolation of the major static isomer yielded an isomer of bisporphyrin bullvalone with a binding affinity for C 60 that was ～2 times larger than that of the nonadapted isomer bisporphyrin bullvalone 41.