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934-56-5

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934-56-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 934-56-5 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 9,3 and 4 respectively; the second part has 2 digits, 5 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 934-56:
(5*9)+(4*3)+(3*4)+(2*5)+(1*6)=85
85 % 10 = 5
So 934-56-5 is a valid CAS Registry Number.
InChI:InChI=1/C6H5.3CH3.Sn/c1-2-4-6-5-3-1;;;;/h1-5H;3*1H3;/rC9H14Sn/c1-10(2,3)9-7-5-4-6-8-9/h4-8H,1-3H3

934-56-5 Well-known Company Product Price

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  • Aldrich

  • (366331)  Trimethyl(phenyl)tin  98%

  • 934-56-5

  • 366331-1G

  • 456.30CNY

  • Detail
  • Aldrich

  • (366331)  Trimethyl(phenyl)tin  98%

  • 934-56-5

  • 366331-5G

  • 1,559.61CNY

  • Detail

934-56-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name trimethyl(phenyl)stannane

1.2 Other means of identification

Product number -
Other names Trimethylphenylstannane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:934-56-5 SDS

934-56-5Relevant articles and documents

Trimethylsilyl-, trimethylgermyl-, and trimethylstannylbenzene chromium tricarbonyl

Seyferth, Dietmar,Alleston, David L.

, p. 417 - 418 (1963)

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Synthesis of Arylstannanes via Palladium-Catalyzed Decarbonylative Coupling of Aroyl Fluorides

Kayumov, Muzaffar,Zhao, Jian-Nan,Mirzaakhmedov, Sharafitdin,Wang, Dong-Yu,Zhang, Ao

supporting information, p. 776 - 781 (2019/11/14)

Aryl stannanes are valuable precursors in organic transformations, but their synthetic methods are limited. Here we present a Pd-catalyzed decarbonylative stannylation of acid fluorides in the absence of exogenous base. Various aryl stannanes were efficiently prepared from bench-stable transition metal catalyst and ligand with broad functional group compatibility and substrate scope including natural products and pharmaceuticals. This protocol was also successfully used to a late-stage diversification of an existing uricosuric drug probenecid. (Figure presented.).

Synthesis of Aryl Trimethylstannane via BF3·OEt2-Mediated Cross-Coupling of Hexaalkyl Distannane Reagent with Aryl Triazene at Room Temperature

Mao, Shuai,Chen, Zhengkai,Wang, Lu,Khadka, Daulat Bikram,Xin, Minhang,Li, Pengfei,Zhang, San-Qi

, p. 463 - 471 (2019/01/10)

BF3·OEt2-mediated cross-coupling of (SnMe3)2 with aryl triazene offers a new strategy for the synthesis of aryl stannane. A variety of synthetically useful aryl trimethylstannanes were produced in moderate to good yields with this metal-free approach. One-pot sequential Stille cross-coupling with different aryl bromides provides a short entry to both symmetrical and unsymmetrical biaryl compounds.

Synthesis of aryl trimethylstannanes from aryl halides: An efficient photochemical method

Chen, Kai,He, Pei,Zhang, Shuai,Li, Pengfei

supporting information, p. 9125 - 9128 (2016/07/21)

An efficient transition-metal-free photochemical method featuring excellent functional group tolerance, mild reaction conditions and short reaction times has been discovered and developed for the synthesis of (hetero)aryl trimethylstannanes from (hetero)aryl halides. A photo-initiated radical chain mechanism was proposed based on preliminary mechanistic studies.

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