94397-79-2

Basic information

• Product Name: (E)-4-iodostyryltrimethylsilane
• Synonyms: (E)-4-iodostyryltrimethylsilane
• CAS NO: 94397-79-2
• Molecular Weight: 302.23
• Mol File: 94397-79-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-4-iodostyryltrimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-iodostyryltrimethylsilane(94397-79-2)
• EPA Substance Registry System: (E)-4-iodostyryltrimethylsilane(94397-79-2)

Safety Data

• Hazardous Substances Data: 94397-79-2(Hazardous Substances Data)

Upstream product

• 1514-50-7 4-iodobenzenediazonium tetrafluoroborate 
• 754-05-2 ethenyltrimethylsilane 
• 938-81-8 N-nitrosoacetanilide 
• 19260-02-7 C₈H₇IN₂O₂ 

Relevant articles and documents

REACTION OF DIAZONIUM SALTS WITH TRANSITION METALS IX. REACTION OF VINYLTRIMETHYLSILANE WITH ARENEDIAZONIUM TETRAFLUOROBORATES UNDER PALLADIUM(0) CATALYSIS

Arenediazonium tetrafluoroborates (ArN2BF4 where Ar = Ph, 4-MeC6H4, 4-BrC6H4, 4-IC6H4 and 4-NO2C6H4) reacted easily with CH2=CHSiMe3 at 25 deg C to give ArCH=CH2, (E)-ArCH=CHSiMe3 and Ar(Me3Si)C=CH2 in excellent yields under palladium(0) catalysis. (E)-ArCH=CHSiMe3 compounds were obtained predominantly and isolated in good yields by using an excess of CH2=CHSiMe3 over ArN2BF4.Protodesilylation of the reaction mixture afforded styrene derivatives.