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949-01-9

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949-01-9 Usage

General Description

1-Morpholino-2-phenyl-1-ethanethione, also known as thiomorpholine, is an organosulfur compound with the chemical formula C11H17NOS. It is a white to pale yellow solid that is used in the synthesis of various pharmaceuticals and as a building block for organic synthesis. Thiomorpholine is a cyclic amine with a sulfur atom in the ring, giving it unique chemical properties. It is commonly employed as a chelating agent and is used in the production of rubber accelerators, corrosion inhibitors, and pharmaceuticals. The compound has a characteristic odor and is considered to be a toxic and irritant substance. Thiomorpholine is used in chemical research and industrial applications, making it an important chemical in the field of organic chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 949-01-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 9,4 and 9 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 949-01:
(5*9)+(4*4)+(3*9)+(2*0)+(1*1)=89
89 % 10 = 9
So 949-01-9 is a valid CAS Registry Number.
InChI:InChI=1/C12H15NOS/c15-12(13-6-8-14-9-7-13)10-11-4-2-1-3-5-11/h1-5H,6-10H2

949-01-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-morpholin-4-yl-2-phenylethanethione

1.2 Other means of identification

Product number -
Other names Phenylacetic acid thiomorpholide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:949-01-9 SDS

949-01-9Relevant articles and documents

Desulfurizing agent for thioamides

Polushina,Zavarzin,Krayushkin,Rodionova,Yarovenko

, p. 383 - 385 (2021/03/03)

Thioamides treated with thionyl chloride in an ionic liquid were successfully converted into amides.

Method for synthesizing thioamide compound from 1,2,3-thiodiazole compound and amine under catalysis of copper

-

Paragraph 0168-0174, (2021/05/12)

The invention belongs to the technical field of organic chemistry, and discloses a method for synthesizing a thioamide compound from a 1,2,3-thiodiazole compound and amine under the catalysis of copper. The method comprises the following steps: in a protective atmosphere, taking an organic solvent as a reaction medium, reacting a 1,2,3-thiodiazole compound with an amine compound under the action of a copper salt catalyst or a copper catalyst and a phosphine ligand, and carrying out subsequent treatment to obtain the thioamide compound. According to the method, the copper salt is used as the catalyst, the phosphine ligand is adopted, the yield is high, and the substrate applicability is wide. In addition, the reaction takes the 1,2,3-thiodiazole compound and the amine compound as raw materials, and has the advantages that the raw materials are cheap and easy to prepare, the operation is simple and convenient, and the atom economy is high.

Transition-Metal-Free Cleavage of C-C Triple Bonds in Aromatic Alkynes with S8 and Amides Leading to Aryl Thioamides

Xu, Kai,Li, Ziyi,Cheng, Fangyuan,Zuo, Zhenzhen,Wang, Tao,Wang, Mincan,Liu, Lantao

supporting information, p. 2228 - 2231 (2018/04/30)

A novel transition-metal-free cleavage reaction of C-C triple bonds in aromatic alkynes with S8 and amides furnishes aryl thioamides in moderate to excellent yields. The remarkable features of this thioamidation include the metal-free cleavage of C-C triple bond, mild reaction conditions, as well as wide substrate scope that is particularly compatible with some internal aromatic alkynes and acetamides.

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