95-95-4Relevant articles and documents
A method for preparing 2, 4, 5 - trichloro phenol (by machine translation)
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Paragraph 0010; 0011; 0013; 0014, (2019/02/27)
The invention discloses a 2, 4, 5 - trichloro phenol industrial preparation method. The 2, 4, 5 - trichloro phenol industrial preparation method, in order to 2, 4 - dichloro nitrobenzene is used as the initial raw materials, by chlorine, reduction and diazo - sandmaier three-step reaction synthesis of 2, 4, 5 - trichloro phenol. The got in the course of 2, 4, 5 - trichloro phenol as yellow solid, purity 97.5%, each step the raw material conversion rate respectively reaches 100%, the whole process of the total yield up to 60%. (by machine translation)
SYNTHESIS OF CLAY-TEMPLATED SUBNANO-SIZED ZERO VALENT IRON (ZVI) PARTICLES, CLAYS CONTAINING SAME, AND USE OF BOTH IN CONTAMINANT TREATMENTS
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Page/Page column 7-8, (2011/06/23)
A clay comprising a 2:1 aluminosilicate clay having negative charge sites, the 2:1 aluminosilicate clay containing subnano-sized zero valent iron (ZVI) particles distributed on clay surfaces is provided. In one embodiment, at least some or all of the particles have a cross-section of five (5) angstroms or less. Methods of synthesizing and the novel clays and the clay-templated subnano-scale ZVI particles themselves are also described. Such novel products are useful in a variety of remediation applications, including for reduction and dechlorination reactions.
Photocatalytic degradation of lindane by polyoxometalates: Intermediates and mechanistic aspects
Antonaraki,Triantis,Papaconstantinou,Hiskia
experimental part, p. 119 - 124 (2010/08/22)
The photocatalytic degradation of lindane (γ-1,2,3,4,5,6-hexachlorocyclohexane) has been studied in the presence of the polyoxometalate PW12O403- in aqueous solutions. Lindane is fully decomposed to CO2, Cl- and H2O, while a great variety of intermediates has been detected using GC-MS, including aromatic compounds (dichlorophenol, trichlorophenols, tetrachlorophenol, hexachlorobenzene, di- and trichloro-benzenodiol), non-aromatic cyclic compounds (penta-, tetrachlorocyclohexene, heptachlorocyclohexane), aliphatic compounds (tetrachloroethane) and condensation products (polychlorinated biphenyls). The number and nature of the intermediates implies that the mechanism of decomposition of lindane is based on both oxidative and reductive processes. Common intermediates have been reported during photolysis of lindane in the presence of titanium dioxide. A similar overall mechanism of polyoxometalates and TiO2 photocatalysis through the formation of common reactive species is suggested.