98487-93-5

Basic information

• Product Name: α-methyl-p-nitrobenzyl hydroperoxide
• Synonyms: α-methyl-p-nitrobenzyl hydroperoxide
• CAS NO: 98487-93-5
• Molecular Weight: 183.164
• Mol File: 98487-93-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: α-methyl-p-nitrobenzyl hydroperoxide(CAS DataBase Reference)
• NIST Chemistry Reference: α-methyl-p-nitrobenzyl hydroperoxide(98487-93-5)
• EPA Substance Registry System: α-methyl-p-nitrobenzyl hydroperoxide(98487-93-5)

Safety Data

• Hazardous Substances Data: 98487-93-5(Hazardous Substances Data)

Upstream product

• 100-12-9 4-ethylnitrobenzene 
• 75-91-2 tert.-butylhydroperoxide 
• 19910-33-9 2-(4-nitrophenyl)propanoic acid 

Downstream Products

• 100-19-6 (4-nitrophenyl)ethanone 
• 100-27-6 2-(4-nitrophenyl)ethanol 

Relevant articles and documents

Benzylic Hydroperoxidation via Visible-Light-Induced Csp3-H Activation

A highly efficient benzylic hydroperoxidation has been realized through a visible-light-induced Csp3-H activation. We believe that this reaction undergoes a direct HAT mechanism catalyzed by eosin Y. This approach features the use of a metal-free catalyst (eosin Y), an energy-economical light source (blue LED), and a sustainable oxidant (molecular oxygen). Primary, secondary, and tertiary hydroperoxides as well as silyl, benzyl, and acyl peroxides were successfully prepared with good yields and excellent functional group compatibility.

LIQUID-PHASE CATALYTIC OXIDATION OF p-NITROETHYLBENZENE

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