98815-40-8

Basic information

• Product Name: 3-amino-3-phenyl-2-propenal
• Synonyms: 3-amino-3-phenyl-2-propenal
• CAS NO: 98815-40-8
• Molecular Weight: 147.177
• Mol File: 98815-40-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-amino-3-phenyl-2-propenal(CAS DataBase Reference)
• NIST Chemistry Reference: 3-amino-3-phenyl-2-propenal(98815-40-8)
• EPA Substance Registry System: 3-amino-3-phenyl-2-propenal(98815-40-8)

Safety Data

• Hazardous Substances Data: 98815-40-8(Hazardous Substances Data)

Upstream product

• 1402610-96-1 benzyl hydroxy(1-phenyl-3-(trimethylsilyl)prop-2-yn-1-yl)carbamate 
• 873-67-6 benzonitrile oxide 
• 14397-33-2 3-phenyl-2-isoxazoline 
• 1006-65-1 3-phenylisoxazole 

Relevant articles and documents

Stereoselective and catalytic access to β-enaminones: An entry to pyrimidines

We describe herein a highly stereoselective access to Cbz-protected β-enaminones 2 based on the NaOH catalyzed rearrangement of propargylic hydroxylamines 1. The synthetic potential of these β-enaminones is illustrated in an original synthesis of pyrimidi

Metal-carbonyl-Induced Reaction of Isoxazoles. Ring Cleavage and Reduction by Hexacarbonylmolybdenum, Pentacarbonyliron, or Nonacarbonyldi-iron

In the presence of and water the isoxazoles (1a-f) undergo thermally induced reductive cleavage of the N-O bond to give β-amino enones in good yield.Similar results were obtained by the use of and water with photoirradiation, or of and water with heating.A mechanism involving an N-complexed isoxazolepentacarbonylmolybdenum or isoxazoletetracarbonyliron, and a - or -complexed (β-oxo vinyl)nitrene intermediate is proposed for the reactions.The complexed nitrene moiety could be reduced by the central metal in the presence of water to give amine.Furthermore, treatment of 2-benzoyl- 3-phenyl-2-H-azirine (8a), which is an isomer of 3,5-diphenylisoxazole, with the metal carbonyls and water also resulted in the formation of a β-amino enone possibly via the corresponding complexed (β-oxo vinyl)nitrene.An N-complexed isoxazole-pentacarbonylmolybdenum intermediate was prepared by the photoreaction of with 3,5-dimethylisoxazole.Its characterization, and chemical transformations, have been carried out to investigate the proposed mechanism.