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CHLOROIODOMETHANE

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Name

CHLOROIODOMETHANE

EINECS 209-804-8
CAS No. 593-71-5 Density 2.343 g/cm3
PSA 0.00000 LogP 1.61770
Solubility N/A Melting Point N/A
Formula CH2ClI Boiling Point 102.2 °C at 760 mmHg
Molecular Weight 176.384 Flash Point 15.6 °C
Transport Information UN 2810 Appearance clear pale yellow to pink-reddish liquid
Safety 26-36-24/25-23 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 593-71-5 (Chloroiodomethane) Hazard Symbols IrritantXi
Synonyms

chloro-iodo-methane;

Article Data 22

CHLOROIODOMETHANE Synthetic route

75-11-6

diiodomethane

A

75-09-2

dichloromethane

B

593-71-5

Chloroiodomethane

Conditions
ConditionsYield
With iodine trichloride Product distribution; further iodoalkanes;A 34%
B 50%
75-11-6

diiodomethane

75-09-2

dichloromethane

593-71-5

Chloroiodomethane

Conditions
ConditionsYield
With aluminium trichloride; potassium chloride at 114℃;
75-11-6

diiodomethane

593-71-5

Chloroiodomethane

Conditions
ConditionsYield
With pyridine; tributyltin chloride at 100℃; Thermodynamic data; Equilibrium constant; Δ G;
With Iodine monochloride
With Iodine monochloride
75-09-2

dichloromethane

593-71-5

Chloroiodomethane

Conditions
ConditionsYield
With methanol; sodium iodide
With methanol; sodium iodide at 130℃;
With methyl iodide; Wilkinson's catalyst at 100℃; for 2h;
With methyl iodide; tris(triphenylphosphine)ruthenium(II) chloride at 100℃; for 2h;
17305-95-2

(chloromethyl)mercury(II) chloride

593-71-5

Chloroiodomethane

Conditions
ConditionsYield
With iodine
74-97-5

chlorobromomethane

A

75-09-2

dichloromethane

B

593-71-5

Chloroiodomethane

Conditions
ConditionsYield
With Amberlyst A-26 (chloride form); methyl iodide at 27 - 70℃; for 9h; Yield given. Yields of byproduct given;
16519-98-5

iodomethyl

593-71-5

Chloroiodomethane

Conditions
ConditionsYield
With chlorine Rate constant; Thermodynamic data; Irradiation; poly(tetrafluoroethylene)-coated Pyrex or uncoated quartz reactor, temperatures 295 - 524 K;
75-09-2

dichloromethane

74-88-4

methyl iodide

A

75-11-6

diiodomethane

B

593-71-5

Chloroiodomethane

Conditions
ConditionsYield
neutral alumina 90 + Bu4P(1+)I(1-) In gas at 195℃; under 760 Torr; for 1.25h;A 36 % Spectr.
B 50 % Spectr.
neutral alumina 90 + Bu4P(1+)I(1-) In gas at 195℃; under 760 Torr;A 9 % Spectr.
B 34 % Spectr.
ClCH2HgI

ClCH2HgI

593-71-5

Chloroiodomethane

Conditions
ConditionsYield
With iodine; potassium iodide
874501-62-9

benzyl-chloromethyl selenide

10034-85-2

hydrogen iodide

A

593-71-5

Chloroiodomethane

B

620-05-3

iodomethylbenzene

CHLOROIODOMETHANE Chemical Properties

IUPAC:chloro(iodo)methane
CAS:593-71-5
The Molecular formula of Chloroiodomethane(593-71-5):CH2ClI
The Molecular Weight of Chloroiodomethane(593-71-5):176.38
Synonyms:METHYLENE CHLOROIODIDE;CHLOROIODOMETHANE;Methane, chloroiodo-;CHLOROIODOMETHANE, STAB.;Chloroiodomethane,98%; Chloroiodomethane, stabilized, 98%;CHLOROIODOMETHANE , STABILIZED WITH COPPER;Chloroiodomethane, 98%, stab. with copper
EINECS:209-804-8
Density:2.422 g/mL at 25oC(lit.)
Boiling Point:108-109oC(lit.)
Flash Point:15.6oC
Vapour Pressure:39.3 mmHg at 25oC
Refractive index:n20/D 1.582(lit.)
storage temp.:0-6oC
Product Categories:Aliphatics;Halides;Alcohol& Phenol& Ethers;omega-Functional Alkanols, Carboxylic Acids, Amines & Halides;omega-Haloalkyl Chlorides;Alkyl;Halogenated Hydrocarbons;Organic Building Blocks
Mol File:593-71-5.mol

CHLOROIODOMETHANE Uses

Chloroiodomethane(593-71-5) is an important intermediate used in organic synthesis.It is aiso used as a versatile organic synthon.

CHLOROIODOMETHANE Safety Profile

Safty informations about Chloroiodomethane(593-71-5):
Hazard Codes:Xi
Risk Statements:36/37/38
 36/37/38(Irritating to eyes, respiratory system and skin)
Safety Statements:26-36-24/25-23
 26(In case of contact with eyes, rinse immediately with plenty of water and seek medical advice)
 36(Wear suitable protective clothing)
 24/25(Avoid contact with skin and eyes)
 23(Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer))
RIDADR:UN2810
WGK Germany:3
F:8
HazardClass:6.1

CHLOROIODOMETHANE Specification

Handling and Storage:
Storage:Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4oC). Store protected from light.
Handling:Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Store protected from light.
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