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Copper phthalocyanine

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Copper phthalocyanine

EINECS 205-685-1
CAS No. 147-14-8 Density 1.62[at 20℃]
PSA 84.02000 LogP 1.46190
Solubility <0.1 g/100 mL at 20 °C in water Melting Point 600 °C (dec.)
Formula C32H16CuN8 Boiling Point N/A
Molecular Weight 576.079 Flash Point N/A
Transport Information N/A Appearance dark blue fine crystalline powder
Safety 22-24/25 Risk Codes R36/37/38; R48; R41; R37/38; R20/21/22
Molecular Structure Molecular Structure of 147-14-8 ((29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)copper) Hazard Symbols Xi,Xn

Chromatex Blue BN;Chromofine Blue4920G;Chromofine Blue 4930PK;Chromofine Blue 4950;Chromofine Blue 4973;Chromofine Blue 5108;Chromofine Blue 5187;Chromofine Blue 5206;Chromofine Blue 6310PK;Chromofine Blue 6335JC;Phthalocyanine blue (6CI);127EPS;402SD;7075M;79S26C;79S26C chip;A220;Acnalin Supra Blue G;Akrochem626;Chromofine Blue A220JC;Chromofine Blue HS 3;Chromofine Blue S 200;Chromofine Blue S 4920;

Article Data 117

Copper phthalocyanine Synthetic route




copper phthalocyanine

With CuCl2*2H2O for 0.166667h; microwave irradiation;98%
With CuCl2*2H2O at 190 - 210℃; for 0.25h; microwave irradiation;88%
With copper diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene at 140℃; for 0.0833333h;76%
With 1,1,1,3,3,3-hexamethyl-disilazane; copper(ll) bromide In N,N-dimethyl-formamide at 100℃; for 10h;74%

phthalic anhydride


copper phthalocyanine

With ammonium molybdate tetrahydrate; urea for 0.0833333h; microwave irradiation;93%
With ammonium molybdate; urea at 200℃; for 0.166667h; microwave irradiation;80%
Stage #1: phthalic anhydride With N,N-dimethyl-formamide; 1,1,1,3,3,3-hexamethyl-disilazane; copper dichloride; toluene-4-sulfonic acid at 150℃; for 10h;
Stage #2: With sulfuric acid



copper phthalocyanine

Stage #1: phthalimide With toluene-4-sulfonic acid; 1,1,1,3,3,3-hexamethyl-disilazane; copper(ll) bromide; N,N-dimethyl-formamide at 150℃; for 10h;
Stage #2: With sulfuric acid

copper phthalocyanine

copper ftalocyanine tetra-3-sulfonyl chloride

With chlorosulfonic acid; thionyl chloride 1.) 138 - 140 deg C, 3 h, 2.) 80 - 85 deg C, 3 h; Multistep reaction;

Copper phthalocyanine Chemical Properties

Molecule structure of Copper phthalocyanine (CAS NO.147-14-8):

Molecular Weight: 576.06904 g/mol
Molecular Formula: C32H16CuN8 
Melting Point: 600°C (dec.)
Water Solubility: <0.1 g/100 mL at 20 °C
H-Bond Acceptor: 8
Exact Mass: 575.079394
MonoIsotopic Mass: 575.079394
Topological Polar Surface Area: 98.9
Heavy Atom Count: 41 
Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=NC(=NC5=NC(=NC6=NC(=NC2=N3)C7=CC=CC=C76)8=CC=CC=C85)C9=CC=CC=C94.[Cu]
InChI: InChI=1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;
EINECS: 205-685-1
Product Categories: Dyes and Pigments; INORGANIC & ORGANIC CHEMICALS; Organometallics; electronic; Classes of Metal Compounds; Cu (Copper) Compounds; Functional Materials; Phthalocyanines; Phthalonitriles & Naphthalonitriles; Transition Metal Compounds; Electroluminescence; Blue needle crystal

Copper phthalocyanine History

 Copper phthalocyanine (CAS NO.147-14-8) was first developed as a pigment in the mid-1930s.

Copper phthalocyanine Uses

 Copper phthalocyanine (CAS NO.147-14-8)'s brilliant blue is frequently used in paints and dyes. Due to its stability, Copper phthalocyanine is also used in inks, coatings, and many plastics. It is a standard pigment used in printing ink and the packaging industry. Copper phthalocyanine is also used as a source material for manufacture of Phthalocyanine Green G. As presently produced, they are highly stable pigments, resistant to crystallization in organic solvents, and essentially free from flocculation in coatings. Both the green and the blue dyes have high tinting power and are used in latex paints and in printing inks, as well as all types of interior and exterior coatings.

Copper phthalocyanine Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD intraperitoneal > 3gm/kg (3000mg/kg) KIDNEY, URETER, AND BLADDER: URINE VOLUME DECREASED

Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(1), Pg. 92, 1985.
rat LD oral > 15gm/kg (15000mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(1), Pg. 92, 1985.

Copper phthalocyanine Safety Profile

Safety Statements: 22-24/25 
S22:Do not breathe dust. 
S24/25:Avoid contact with skin and eyes.
RTECS: GL8510000
Low toxicity by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic vapors of NOx and Cu.

Copper phthalocyanine Specification

 Copper phthalocyanine (CAS NO.147-14-8) is also named as AI3-26192 ; Accosperse Cyan Blue GT ; Aqualine Blue ; Arlocyanine Blue PS ; Bahama Blue BC ; Bahama Blue BNC ; Bahama Blue Lake NCNF ; Bahama Blue WD ; Bermuda Blue ; Blue GLA ; Blue Toner GTNF ; Blue pigment ; C.I. 74160 l C.I. Ingrain Blue 2 ; CI Ingrain Blue 2 ; CI Pigment Blue 15 ; Copper Phthaloycanine Blue ; Copper phthalocyanin ; Copper tetrabenzoporphyrazine ; Copper(2+) phthalocyanine ; Copper(II) phthalocyanine ; Copper, (29H,31H-phthalocyaninato(2-)- ; Cromophtal Blue 4GN ; Cromophtal Blue GF ; Cyan Blue BNC 55-3745 ; Cyan Blue BNF 55-3753 ; Cyan Blue GT ; Cyan Blue GT 55-3295 ; Cyan Blue GT 55-3300 ; Cyan Blue GTNF ; Cyan Blue Toner GT 3000 ; Cyan Blue XR 55-3758 ; Cyanine Blue HB ; Cyanine Blue LBG ; Cyanine Blue Rnf ; Dainichi Cyanine Blue B ; Fastogen Blue BS ; Fastogen Blue BSF ; Graphtol Blue BL ; Graphtol Blue BLF ; HSDB 2925 ; Helio Blue B ; Helio Fast Blue B ; Heliogen Blue BWS ; Isol Phthalo Blue BT ; Isol Phthalo Blue CBG ; Isol Phthalo Blue E 7543 ; Monarch Blue NCNF X-2658 ; Monarch Blue Toner NC X-2371 ; Monarch Blue Toner NCNF X-2810 ; Monarch Blue Toner X-2303 ; Monarch Blue Toner X-2763 ; NSC 15976 ; UNII-3VEX9T7UT5 . Copper phthalocyanine (CAS NO.147-14-8) has the appearance of a blue powder, insoluble in water and most solvents.

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