Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

D(+)-Phenylalaninol

Related Products

Hot Products

Name

D(+)-Phenylalaninol

EINECS 226-086-1
CAS No. 5267-64-1 Density 1.201 g/cm3
PSA 46.25000 LogP 1.24900
Solubility N/A Melting Point 93-95 °C(lit.)
Formula C9H13NO Boiling Point 307.5 °C at 760 mmHg
Molecular Weight 151.208 Flash Point 139.8 °C
Transport Information UN 3259 8/PG 3 Appearance white to light yellow crystal powder
Safety 26-36/37/39-45-27 Risk Codes 34
Molecular Structure Molecular Structure of 5267-64-1 (D(+)-Phenylalaninol) Hazard Symbols CorrosiveC, IrritantXi
Synonyms

1-Propanol,2-amino-3-phenyl-, (R)-(+)- (8CI);Benzenepropanol, b-amino-, (R)-;((1R)-1-Hydroxymethyl-2-phenylethyl)amine;(2R)-2-Amino-3-phenylpropan-1-ol;(R)-(+)-2-Amino-3-phenyl-1-glycinol;(R)-(+)-2-Amino-3-phenylpropanol;(R)-(+)-Phenylalaninol;(R)-1-(Hydroxymethyl)-2-phenylethylamine;(R)-2-Amino-3-phenyl-1-propanol;(R)-2-Amino-3-phenylpropanol;(R)-3-Phenyl-2-amino-1-propanol;(bR)-b-Aminobenzenepropanol;D-Phenylalaninol;

Article Data 116

D(+)-Phenylalaninol Synthetic route

673-06-3

D-(R)-phenylalanine

5267-64-1

(R)-2-amino-3-phenylpropanol

Conditions
ConditionsYield
With lithium borohydride; chloro-trimethyl-silane In tetrahydrofuran at 20℃; for 0.25h; Reduction;99%
With sodium tetrahydroborate; iodine In tetrahydrofuran at 0℃; Reflux;99%
With sodium tetrahydroborate; sulfuric acid In tetrahydrofuran at 20℃;98%

(R)-N-(1-hydroxy-3-phenylpropan-2-yl)acetamide

5267-64-1

(R)-2-amino-3-phenylpropanol

Conditions
ConditionsYield
With sulfuric acid In water at 120℃;98%
With sulfuric acid at 100℃; for 48h; Darkness;143.7 mg

(R)-2-amino-3-phenylpropionitrile hydrochloride

A

5267-64-1

(R)-2-amino-3-phenylpropanol

B

85612-59-5

(R)-3-phenylpropane-1,2-diamine

Conditions
ConditionsYield
With hydrogenchloride; methanol; water; hydrogen; 5% palladium over charcoal at 35℃; under 6750.68 - 22502.3 Torr; for 43h;A 91%
B 6%
40217-17-2, 90719-32-7, 120574-96-1, 102029-44-7

(R)-4-(phenylmethyl)-2-oxazolidinone

5267-64-1

(R)-2-amino-3-phenylpropanol

Conditions
ConditionsYield
With ammonium bromide; 3-azapentane-1,5-diamine at 90℃; for 5h; Microwave irradiation;84%
130406-30-3

9H-fluoren-9-ylmethyl (R)-<1-(hydroxymethyl)-2-phenylethyl>carbamate

5267-64-1

(R)-2-amino-3-phenylpropanol

Conditions
ConditionsYield
With piperidine In dichloromethane for 1h; Ambient temperature;82%
21685-51-8

D-phenylalanine methyl ester

5267-64-1

(R)-2-amino-3-phenylpropanol

Conditions
ConditionsYield
With methanol; sodium tetrahydroborate at 0 - 10℃; for 1h; Temperature; Solvent;81%

(1R,1'R)-N,1'-dibenzyl-1-phenyl-2,2'-dihydroxydiethylamine

5267-64-1

(R)-2-amino-3-phenylpropanol

Conditions
ConditionsYield
With ammonium formate; palladium on activated charcoal In methanol for 2h; Heating;80%
152903-44-1

(+)-(R)-2-(1-benzyl-2-hydroxyethyl)-1H-isoindole-1,3(2H)-dione

5267-64-1

(R)-2-amino-3-phenylpropanol

Conditions
ConditionsYield
With hydrazine hydrate In acetonitrile for 4h; Heating;73%
5267-64-1

(R)-2-amino-3-phenylpropanol

Conditions
ConditionsYield
Stage #1: rac-phenylalaninol With O,O'-dibenzoyl-L-tartaric acid In acetone at 25℃; for 6h;
Stage #2: With potassium hydroxide In dichloromethane
52%
3182-93-2

(L)-phenylalanine ethyl ester hydrochloride

A

3182-95-4

L-Phenylalaninol

B

5267-64-1

(R)-2-amino-3-phenylpropanol

Conditions
ConditionsYield
With methanol; Na/SiO2 In tetrahydrofuran at 0 - 25℃; Bouveault-Blanc reduction; Inert atmosphere; optical yield given as %ee;A 27%
B n/a

D(+)-Phenylalaninol Chemical Properties

Molecular Structure:

Molecular Formula: C9H13NO
Molecular Weight: 151.2056
IUPAC Name: 2-Amino-3-phenylpropan-1-ol
Synonyms of D(+)-Phenylalaninol (CAS NO.5267-64-1): EINECS 226-086-1 ; (R)-2-Amino-3-phenylpropanol
CAS NO: 5267-64-1
Product Categories: Pharmaceutical Intermediates ; chiral ; Phenylalanine [Phe, F] ; Amino Alcohols (Chiral) ; Chiral Building Blocks ; Synthetic Organic Chemistry ; Amino alcohols
Melting point: 93-95 °C
Index of Refraction: 1.561
Molar Refractivity: 45.46 cm3
Molar Volume: 140.3 cm3
Surface Tension: 46.6 dyne/cm
Density: 1.077 g/cm3
Flash Point: 137.5 °C
Enthalpy of Vaporization: 57.46 kJ/mol
Boiling Point: 303.8 °C at 760 mmHg
Vapour Pressure: 0.0004 mmHg at 25°C

D(+)-Phenylalaninol Uses

 D(+)-Phenylalaninol (CAS NO.5267-64-1) is the Dextrorotatory form of the amino acid, Phenylalanine. It is not absorbed into the body. It acts as an inhibiting agent to the enzymes which are responsible for the breakdown of endorphins.

D(+)-Phenylalaninol Safety Profile

Hazard Codes of D(+)-Phenylalaninol (CAS NO.5267-64-1): CorrosiveC,IrritantXi
Risk Statements: 34
R34: Causes burns.
Safety Statements: 26-36/37/39-45-27
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S27: Take off immediately all contaminated clothing.
RIDADR: UN 3259 8/PG 3
WGK Germany: 3
F: 10-23

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 5267-64-1