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Enzyme

    Name:
    Enzyme
    Detailed information:
    Any of a unique class of proteins that catalyze a broad spectrum of biochemical reactions. Enzymes are formed in living cells; they are comprised one or more polypeptide chains with molecular weight from 10,000 to a million or more. An important characteristic of enzymes is their specificity, i.e., a given enzyme can catalyze one particular reaction and no others. Six types are recognized, which catalyze the following reactions: (1) redox (oxidoreductases), (2) transfer of specific radicals or groups (transferases), (3) hydrolysis (proteolytic), (4) removal from or addition to the substrate of specific chemical groups (lyases), (5) isomerizaton (isomerases), (6) combination or binding together of substrate units (ligases). The names of enzymes invariably terminate in either -ase or -in. The following partial list indicates some of the more important functions performed by enzymes; among these are the ability to cleave the peptide bonds of proteins (hydrolysis) with simultaneous formation of water; and to decompose sugars and starches to ethyl alcohol and carbon dioxide (fermentation). Enzymes are essential to many biochemical processes, especially in the food, beverage, and pharmaceutical industries.


    amylase

    starch hydrolysis

    carboxylase

    decomposes pyruvic acid

    cellulase

    converts cellulose to glucose

    cholinesterase

    inactivates acetylcholine

    chymotrypsin

    hydrolysis of proteins

    invertase

    converts sucrose to glucose and fructose

    lipase

    hydrolysis of fats

    maltase

    converts maltose to glucose

    pepsin

    hydrolysis of proteins

    protease

    hydrolysis of peptide linkages

    rennin

    hydrolysis of proteins

    ribonuclease

    decomposes RNA

    trypsin

    splits proteins to amino acids

    urease

    decomposes urea to NH4 and CO2.

    zymase

    converts sugars to alcohol and CO2 (fermentation)


    Recent research in biomimetic chemistry has succeeded in creating synthetic enzymes that imitate the behavior of natural enzymes, e.g., chymotrypsin, and are almost as effective. See Catalyst; Biomimetic Chemistry; Fermentation; Hydrolysis.
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