A higher than normal energy level of the electrons of an atom, radical, or molecule, typically resulting from absorption of photons (quanta) from a radiation source (arc, flame, spark, etc.) in any wavelength of the electromagnetic spectrum. X-ray, UV, visible, infrared, microwave, and radio frequencies are used for excitation in various types of spectroscopy. When the energizing source is removed or discontinued, the atom or molecule returns to its normal or stable state either by emitting the absorbed photons or by transferring the energy to other atoms or molecules. The emission by the atom or molecule yields line or band spectra characteristic of its structure, thus permitting identification. Photochemical reactions are induced by excited chemical entities, which are also responsible for the phenomena of luminescence (phosphorescence and fluorescence).See Spectroscopy; Photochemistry; Absorption (Biology) (2).