(phosphonitrile). A ring or chain polymer that contains alternating phosphorus and nitrogen atoms with two substituents on each phosphorus atom. Characteristic structures are cyclic trimers, cyclic tetramers, and high polymers. The substituent can be any of a wide variety of organic groups, halogen, amino, etc. Most cyclic trimers are crystalline, solids, organosoluble, and stable to weather conditions; the high polymers (polyphosphazenes) are elastomeric or thermoplastic. A copolymer of phosphazene and styrene has been investigated for use as a flame-retardant.
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