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Trichloromethyl Chloroformate

    Name:
    Trichloromethyl Chloroformate
    Detailed information:
    Chemistry name:diphosgene
    M Formula:ClCOOCCl3
     
    Properties:
    Colorless liquid; odor similar to phosgene (newly mown hay). D 1.65 (15C), bp 127–128C, fp −57C, vap d 6.9 (air = 1), refr index 1.45664 (22C). Decomposed by heat, porous substances, activated carbons (with evolution of phosgene), also by alkalies, hot water. Soluble in alcohol, benzene, and ether. Noncombustible.
     
    Derivation:
    (1) By chlorinating methyl formate, (2) by chlorinating methyl chloroformate. In both methods the mixture of chloro-derivatives is then separated by fractionation.
     
    Grade:
    Technical.
     
    Hazard:
    Toxic by inhalation and ingestion, strong irritant to tissue.
     
    Use:
    Organic synthesis, military poison gas.
     

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