Of a chemical compound, the state in which not all the available valence bonds along the alkyl chain are satisfied; in such compounds the extra bonds usually form double or triple bonds (chiefly with carbon). Thus, unsaturated compounds are more reactive than saturated compounds because other elements readily add to the unsaturated linkage. An unsaturated compound (ethylene, C2H4; butadiene, C4H6; benzene, C6H6) has fewer hydrogen atoms or equivalent groups than the corresponding saturated compound (ethane, C2H6; butane, C4H10; cyclohexane, C6H12).In structural formulas unsaturation may be represented by parallel lines joining the carbon atoms (ethylene, H2C═CH2; butadiene H2C═CHCH═CH2) or by colons or triple dots, H2C:CH2H2C:CH2 (ethylene) and HC…CH (acetylene). See Carboxyl Group.
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