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Diethylene glycol bis-glycidyl ether

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Name

Diethylene glycol bis-glycidyl ether

EINECS N/A
CAS No. 4206-61-5 Density 1.165g/cm3
PSA 52.75000 LogP -0.16620
Solubility N/A Melting Point N/A
Formula C10H18 O5 Boiling Point 313°Cat760mmHg
Molecular Weight 218.25 Flash Point 127.3°C
Transport Information N/A Appearance N/A
Safety Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS. Risk Codes 19
Molecular Structure Molecular Structure of 4206-61-5 (DIETHYLENGLYKOL-DIGLYCIDYLETHER) Hazard Symbols N/A
Synonyms

Ether,bis[2-(2,3-epoxypropoxy)ethyl] (6CI,7CI,8CI); 4,7,10-Trioxatridecane,1,2:12,13-diepoxy-; Diethylene glycol bis-glycidyl ether; Diethylene glycoldiglycidyl ether; Diglycidyl diethyleneglycol ether; NSC 517936

Article Data 8

Diethylene glycol bis-glycidyl ether Synthetic route

57947-82-7

bis(allyloxy)diethylene glycol

4206-61-5

diethylene glycol diglycidyl ether

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 24h; Inert atmosphere;98%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; for 24h;
106-89-8

epichlorohydrin

111-46-6

diethylene glycol

4206-61-5

diethylene glycol diglycidyl ether

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate at 40℃; for 0.75h;68%
With sodium hydroxide; tetrabutyl-ammonium chloride In water at 40℃; for 0.75h;33.7%
Stage #1: diethylene glycol
Stage #2: epichlorohydrin
4206-61-5

diethylene glycol diglycidyl ether

540-63-6

ethane-1,2-dithiol

1273318-55-0

C12H24O5S2

Conditions
ConditionsYield
With N-benzyl-trimethylammonium hydroxide at 25℃; for 0.5h; Neat (no solvent); regiospecific reaction;94%
4206-61-5

diethylene glycol diglycidyl ether

1,13-dihydrazino-4,7,10-trioxatridecane-2,12-diol

Conditions
ConditionsYield
With hydrazine hydrate In chloroform at 10℃; for 60h;86%
4206-61-5

diethylene glycol diglycidyl ether

111-26-2

hexan-1-amine

92237-83-7

1-Hexylamino-3-{2-[2-(3-hexylamino-2-hydroxy-propoxy)-ethoxy]-ethoxy}-propan-2-ol

Conditions
ConditionsYield
at 120℃; for 4h;85%
4206-61-5

diethylene glycol diglycidyl ether

103-71-9

phenyl isocyanate

1,9-bis(3-phenyloxazolidin-2-on-5-yl)-2,5,8-trioxanonane

Conditions
ConditionsYield
Stage #1: diethylene glycol diglycidyl ether With Tributylphosphine oxide; lithium bromide In toluene for 2h; Heating;
Stage #2: phenyl isocyanate In toluene for 18h; Heating; Further stages.;
83%
4206-61-5

diethylene glycol diglycidyl ether

C10H20N6O5

Conditions
ConditionsYield
With sodium azide; ammonium chloride In methanol; water at 80℃; for 24h;83%
With sodium azide In methanol; water at 80℃;
4206-61-5

diethylene glycol diglycidyl ether

111-36-4

n-butyl isocyanide

1,9-bis(3-butyloxazolidin-2-on-5-yl)-2,5,8-trioxanonane

Conditions
ConditionsYield
Stage #1: diethylene glycol diglycidyl ether With Tributylphosphine oxide; lithium bromide In toluene for 2h; Heating;
Stage #2: n-butyl isocyanide In toluene for 21h; Heating; Further stages.;
80%
75-15-0

carbon disulfide

4206-61-5

diethylene glycol diglycidyl ether

1,9-bis(oxathiolane-2-thione-5-yl)-2,5,8-trioxanonane

Conditions
ConditionsYield
Stage #1: diethylene glycol diglycidyl ether With lithium bromide In dichloromethane for 2h; Heating;
Stage #2: carbon disulfide In dichloromethane for 16h; Heating; Further stages.;
79%
75-15-0

carbon disulfide

4206-61-5

diethylene glycol diglycidyl ether

103-71-9

phenyl isocyanate

5-(9-oxathiolan-2-thione-2,5,8-trioxanonan-5-yl)-3-phenyloxazolidin-2-one

Conditions
ConditionsYield
Stage #1: diethylene glycol diglycidyl ether With lithium bromide In tetrahydrofuran for 0.5h; Inert atmosphere; Reflux;
Stage #2: phenyl isocyanate In tetrahydrofuran Inert atmosphere; Reflux;
Stage #3: carbon disulfide In tetrahydrofuran at 20℃; for 10h; Inert atmosphere;
73%

Diethylene glycol bis-glycidyl ether Chemical Properties

Chemical Name: Diethylenglykol-diglycidylether
IUPAC NAME: 2-[2-[2-(Oxiran-2-ylmethoxy)ethoxy]ethoxymethyl]oxirane
CAS No.: 4206-61-5
EINECS: 224-122-0
RTECS: KN2330000
Molecular Formula: C10H18O5
Molecular Weight: 218.25 g/mol
Density: 1.165 g/cm3 
Flash Point: 127.3 °C
Boiling Point: 313 °C at 760 mmHg
Following is the structure of Diethylene glycol bis-glycidyl ether (4206-61-5):


The chemical synonymous of Diethylene glycol bis-glycidyl ether (4206-61-5) are Diethylenglykol-diglycidylether ; 2,2’-(Oxybis(2,1-ethanediyloxymethylene))bis-oxiran ; 2,2’-(Oxybis(2,1-ethanediyloxymethylene))bisoxirane ;  Diglycidyldiethyleneglycolether ;  2,2'-[Oxybis(ethyleneoxymethylene)]bisoxirane ; Diglycidyl diglycol

Diethylene glycol bis-glycidyl ether Toxicity Data With Reference

1.    

cyt-rat-ipr 100 mg/kg

    BJPCAL    British Journal of Pharmacology and Chemotherapy. 6 (1951),235.

Diethylene glycol bis-glycidyl ether Consensus Reports

Glycol ether compounds are on the Community Right-To-Know List.

Diethylene glycol bis-glycidyl ether Safety Profile

Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.

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