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Name |
Ethene, 1,1-diethoxy- |
EINECS | N/A |
CAS No. | 2678-54-8 | Density | 0.859 g/cm3 |
PSA | 18.46000 | LogP | 1.53060 |
Solubility | N/A | Melting Point |
N/A |
Formula | C6H12O2 | Boiling Point | 105.645 °C at 760 mmHg |
Molecular Weight | 116.16 | Flash Point | 7.004 °C |
Transport Information | UN 1993 3/PG 3 | Appearance | N/A |
Safety | 23 | Risk Codes | 10 |
Molecular Structure | Hazard Symbols | N/A | |
Synonyms |
Ketene,diethyl acetal (6CI,7CI,8CI);1,1-Diethoxyethylene;Diethylketene acetal; |
Article Data | 28 |
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 130 - 140℃; under 100 Torr; | 92% |
With potassium tert-butylate for 0.1 - 0.183333h; Cooling with ice; | 72% |
With potassium tert-butylate at 20℃; Reflux; Inert atmosphere; | 69.9% |
ketene diethyl acetal
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium tert-butylate In tetrahydrofuran at 0℃; for 2h; Elimination; | 70% |
β-(1,1-diethoxy-ethoxy)-chalcone
A
ketene diethyl acetal
B
1,3-diphenylpropanedione
Conditions | Yield |
---|---|
at 140℃; under 38 Torr; |
Conditions | Yield |
---|---|
With aluminium tert-butyl oleate at 180℃; |
1,1-diethoxy-2-iodoethane
ketene diethyl acetal
Conditions | Yield |
---|---|
With potassium tert-butylate | |
With potassium tert-butylate |
ketene diethyl acetal
Conditions | Yield |
---|---|
With sodium methylate for 0.666667h; Ambient temperature; Yield given; |
ketene diethyl acetal
Conditions | Yield |
---|---|
With sodium; benzene |
The Ethene, 1,1-diethoxy-, with the CAS registry number 2678-54-8, is also known as Ketene, diethyl acetal. This chemical's molecular formula is C6H12O2 and molecular weight is 116.16. What's more, both its IUPAC name and systematic name are the same which is called 1,1-Diethoxyethene. When you are dealing with this chemical, you should be very careful. This chemical is flammable. Therefore, you can not breathe the gas/fumes/vapour/spray.
Physical properties about Ethene, 1,1-diethoxy- are: (1)ACD/LogP: 1.195; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.20; (4)ACD/LogD (pH 7.4): 1.20; (5)ACD/BCF (pH 5.5): 4.77; (6)ACD/BCF (pH 7.4): 4.77; (7)ACD/KOC (pH 5.5): 106.42; (8)ACD/KOC (pH 7.4): 106.42; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 4; (12)Polar Surface Area: 18.46 Å2; (13)Index of Refraction: 1.402; (14)Molar Refractivity: 32.905 cm3; (15)Molar Volume: 135.196 cm3; (16)Polarizability: 13.044×10-24cm3; (17)Surface Tension: 22.788 dyne/cm; (18)Density: 0.859 g/cm3; (19)Flash Point: 7.004 °C; (20)Enthalpy of Vaporization: 33.033 kJ/mol; (21)Boiling Point: 105.645 °C at 760 mmHg; (22)Vapour Pressure: 34.079 mmHg at 25 °C.
Preparation of Ethene, 1,1-diethoxy-: this chemical can be prepared by 2-bromo-1,1-diethoxy-ethane. This reaction needs reagent t-BuOK at temperature of 120-130 °C.
Uses of Ethene, 1,1-diethoxy-: it is used to produce other chemicals. For example, it can react with acrylic acid methyl ester to get 2.2-Diethoxy-cyclobutancarbonsaeuremethylester. The reaction occurs with solvent acetonitrile and other condition of heating for 8 days. The yield is 17 %.
You can still convert the following datas into molecular structure:
(1) SMILES: CCOC(=C)OCC
(2) InChI: InChI=1S/C6H12O2/c1-4-7-6(3)8-5-2/h3-5H2,1-2H3
(3) InChIKey: VTGIVYVOVVQLRL-UHFFFAOYSA-N