Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Ethene, 1,1-diethoxy-

Related Products

Hot Products

Name

Ethene, 1,1-diethoxy-

EINECS N/A
CAS No. 2678-54-8 Density 0.859 g/cm3
PSA 18.46000 LogP 1.53060
Solubility N/A Melting Point N/A
Formula C6H12O2 Boiling Point 105.645 °C at 760 mmHg
Molecular Weight 116.16 Flash Point 7.004 °C
Transport Information UN 1993 3/PG 3 Appearance N/A
Safety 23 Risk Codes 10
Molecular Structure Molecular Structure of 2678-54-8 (KETENE DIETHYL ACETAL) Hazard Symbols N/A
Synonyms

Ketene,diethyl acetal (6CI,7CI,8CI);1,1-Diethoxyethylene;Diethylketene acetal;

Article Data 28

Ethene, 1,1-diethoxy- Synthetic route

2032-35-1

Bromoacetaldehyde diethyl acetal

2678-54-8

ketene diethyl acetal

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 130 - 140℃; under 100 Torr;92%
With potassium tert-butylate for 0.1 - 0.183333h; Cooling with ice;72%
With potassium tert-butylate at 20℃; Reflux; Inert atmosphere;69.9%
XCH2CH(OCH2CH3)2

XCH2CH(OCH2CH3)2

2678-54-8

ketene diethyl acetal

Conditions
ConditionsYield
With 18-crown-6 ether; potassium tert-butylate In tetrahydrofuran at 0℃; for 2h; Elimination;70%
855175-05-2

β-(1,1-diethoxy-ethoxy)-chalcone

A

2678-54-8

ketene diethyl acetal

B

120-46-7

1,3-diphenylpropanedione

Conditions
ConditionsYield
at 140℃; under 38 Torr;
78-39-7

Triethyl orthoacetate

2678-54-8

ketene diethyl acetal

Conditions
ConditionsYield
With aluminium tert-butyl oleate at 180℃;
865-47-4

potassium tert-butylate

51806-20-3

1,1-diethoxy-2-iodoethane

2678-54-8

ketene diethyl acetal

51806-20-3

1,1-diethoxy-2-iodoethane

2678-54-8

ketene diethyl acetal

Conditions
ConditionsYield
With potassium tert-butylate
With potassium tert-butylate

1,1-Diethoxy-ethylamine; hydrochloride

2678-54-8

ketene diethyl acetal

Conditions
ConditionsYield
With sodium methylate for 0.666667h; Ambient temperature; Yield given;
orthobromoacetic acid triethyl ester

orthobromoacetic acid triethyl ester

2678-54-8

ketene diethyl acetal

Conditions
ConditionsYield
With sodium; benzene
40070-39-1

triethyl bromoorthoacetate

71-43-2

benzene

sodium

sodium

2678-54-8

ketene diethyl acetal

75-85-4

tert-Amyl alcohol

1634-04-4

tert-butyl methyl ether

107-21-1

ethylene glycol

621-62-5

chloroacetaldehyde diethyl acetal

2678-54-8

ketene diethyl acetal

Conditions
ConditionsYield
With potassium hydroxide In Dimethyl ether

Ethene, 1,1-diethoxy- Specification

The Ethene, 1,1-diethoxy-, with the CAS registry number 2678-54-8, is also known as Ketene, diethyl acetal. This chemical's molecular formula is C6H12O2 and molecular weight is 116.16. What's more, both its IUPAC name and systematic name are the same which is called 1,1-Diethoxyethene. When you are dealing with this chemical, you should be very careful. This chemical is flammable. Therefore, you can not breathe the gas/fumes/vapour/spray. 

Physical properties about Ethene, 1,1-diethoxy- are: (1)ACD/LogP: 1.195; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.20; (4)ACD/LogD (pH 7.4): 1.20; (5)ACD/BCF (pH 5.5): 4.77; (6)ACD/BCF (pH 7.4): 4.77; (7)ACD/KOC (pH 5.5): 106.42; (8)ACD/KOC (pH 7.4): 106.42; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 4; (12)Polar Surface Area: 18.46 Å2; (13)Index of Refraction: 1.402; (14)Molar Refractivity: 32.905 cm3; (15)Molar Volume: 135.196 cm3; (16)Polarizability: 13.044×10-24cm3; (17)Surface Tension: 22.788 dyne/cm; (18)Density: 0.859 g/cm3; (19)Flash Point: 7.004 °C; (20)Enthalpy of Vaporization: 33.033 kJ/mol; (21)Boiling Point: 105.645 °C at 760 mmHg; (22)Vapour Pressure: 34.079 mmHg at 25 °C.

Preparation of Ethene, 1,1-diethoxy-: this chemical can be prepared by 2-bromo-1,1-diethoxy-ethane. This reaction needs reagent t-BuOK at temperature of 120-130 °C.

Ethene, 1,1-diethoxy- can be prepared by 2-bromo-1,1-diethoxy-ethane.

Uses of Ethene, 1,1-diethoxy-: it is used to produce other chemicals. For example, it can react with acrylic acid methyl ester to get 2.2-Diethoxy-cyclobutancarbonsaeuremethylester. The reaction occurs with solvent acetonitrile and other condition of heating for 8 days. The yield is 17 %.

Ethene, 1,1-diethoxy- can react with acrylic acid methyl ester to get 2.2-Diethoxy-cyclobutancarbonsaeuremethylester.

You can still convert the following datas into molecular structure:
(1) SMILES: CCOC(=C)OCC
(2) InChI: InChI=1S/C6H12O2/c1-4-7-6(3)8-5-2/h3-5H2,1-2H3
(3) InChIKey: VTGIVYVOVVQLRL-UHFFFAOYSA-N

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 2678-54-8